個(gè)人履歷
廖建 博士，研究員，博士生導(dǎo)師。1972年2月生于四川成都。1994年畢業(yè)于上海交通大學(xué)應(yīng)用化學(xué)系， 2002年在中科院成都有機(jī)所獲理學(xué)博士學(xué)位。2003年至2006年在美國(guó)賓州州立大學(xué)材料系、化學(xué)系從事導(dǎo)電高分子、彈性體材料設(shè)計(jì)及性能研究和手性膦配體設(shè)計(jì)及不對(duì)稱(chēng)催化氫化研究。2006年2月回國(guó)后被聘為中科院成都有機(jī)所研究員，并任不對(duì)稱(chēng)合成與手性技術(shù)四川省重點(diǎn)實(shí)驗(yàn)室常務(wù)副主任，所學(xué)位評(píng)定委員會(huì)委員。2008年入選中國(guó)科學(xué)院“西部之光”人才計(jì)劃，2009年入選四川省學(xué)術(shù)和技術(shù)帶頭人后備人選。2010年9月調(diào)入中科院成都生物所任研究員。2012年入選四川省百人計(jì)劃。2014年任天然藥物與臨床轉(zhuǎn)化實(shí)驗(yàn)室主任�，F(xiàn)主要從事新型手性配體設(shè)計(jì)、發(fā)展新不對(duì)稱(chēng)催化方法以及將所發(fā)展的方法應(yīng)用于天然產(chǎn)物合成的研究工作。在國(guó)際核心學(xué)術(shù)刊物（包括J. Am. Chem. Soc.,Angew. Chem. Int. Ed.,Adv. Catal. & Synth.,Macromolecules,Chem. Eur. J.等）上發(fā)表學(xué)術(shù)論著20余篇，獲準(zhǔn)和申請(qǐng)了發(fā)明專(zhuān)利近10項(xiàng)。研究方向
手性配體的設(shè)計(jì)及不對(duì)稱(chēng)催化反應(yīng)方法學(xué)、天然產(chǎn)物合成方法學(xué)代表論著
(31) Liyin Jiang, Tao Jia, Min Wang, Jian Liao, and Peng Cao* “Pd-Catalyzed Enantioselective Hydroalkoxylation of Alkoxyallenes with Phenol for Construction of Acyclic O,O-Acetals” Org. Lett., 2015, 17 ,1070.(30) Tao Jia, Peng Cao, Ding Wang, Yazhou Lou, Jian Liao* “Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of C-Sn Bond”Chem. Eur. J.2015,21, 4918.(29) Juanjuan Wang, Bing wang, Peng Cao, Jian Liao* “Rhodium Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to β,γ-Unsaturated α-Keto Ester Using Chiraltert-Butanesulfinylphosphines Ligands”Tetrahedron Lett.2014,55, 3450.(28) Juanjuan Wang, Min Wang, Peng Cao, Liyin Jiang, Guihua Chen, Jian Liao* “Rh-Catalyzed Asymmetric Arylation ofβ,γ-Unsaturated α-Ketoamides for the Construction of Nonracemic γ,γ-Diarylcarbonyls”Angew. Chem. Int. Ed.2014, 53, 6673. (Highlighted bySynfacts,2014, 1042)(27) Le Du, Peng Cao, Jian Liao* “Bifunctional Ligand Promoted Pd-Catalyzed Asymmetric Allylic Etherification/Amination”Acta Chimica Sinica2013,71, 1239.(26) Le Du, Peng Cao, Junwei Xing, Yazhou Lou, Liyin Jiang, Liangchun Li, Jian Liao* “Hydrogen Bond Promoted Palladium-Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands”Angew. Chem. Int. Ed.2013, 52, 4207.(25) Jiangyang Gui, Guihua Chen, Peng Cao, Jian Liao* “Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins”Tetrahedron: Asymmetry2012, 23,554.(24) Junwei Xing, Peng Cao, Jian Liao* “Chiral SO/P hybrid ligands: an enantioselective switch in palladium-catalyzed asymmetric allylic etherifications”Tetrahedron: Asymmetry2012,23,527.(23) Guihua Chen, Jiangyang Gui, Peng Cao, Jian Liao* “Chiral sulfoxideeolefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions”Tetrahedron2012, 68,3220.(22)Guihua Chen, Junwen Xing, Peng Cao, Jian Liao* “Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones”Tetrahedron2012, 68,5908.(21)Junwen Xing, Guihua Chen, Peng Cao and Jian Liao* “Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indolylnitroalkenes”Eur. J. Org. Chem.2012, 1230.(20) Xiangyang Zhang, Guihua Chen, Peng Cao, Jibing Liu and Jian Liao* “Rhodium-Catalyzed Michael Addition of Arylboronic Acids to 3-Alkylenyloxindoles: Asymmetric Synthesis of Functionalized Oxindoles”Tetrahedron Lett.2012,53, 438.(19) Guihua Chen, Jiangyang Gui, Liangchun Li and Jian Liao* “Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in the Rh-Catalyzed Asymmetric Conjugate Additions”Angew. Chem. Int. Ed.2011, 50, 7681 (hot paper, Highlight bySynfacts,2011, 1193 ).(18) Fuzhong Han,Guihua Chen, Xiangyang Zhang,and Jian Liao*“Chiral Hetero-Disulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones”Eur. J. Org. Chem.2011, 2928.(17) Feng Lang, Guihua Chen, Liangchun Li, Junwen Xing, Fuzhong Han, Linfeng Cun, and Jian Liao* “Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to 2-Nitrostyrenes bytert-Butanesulfinylphosphine Ligand”Chem. Eur. J.2011, 5242 (Highlight bySynfacts,2011, 882).(16) Jibing Liu, Guihua Chen, Junwei Xing and Jian Liao* “tert-Butanesulfinylthioether ligands: synthesis and application in palladium-catalyzed asymmetric allylic alkylation”Tetrahedron: Asymmetry2011,22, 575.(15) Xiangyang Zhang,Jun Chen,Fuzhong Han,Linfeng Cun, and Jian Liao*“Rhodium-Catalyzed Enantioselective Conjugate Addition of Sodium Tetraaryl-borates to 2,3-Dihydro-4-Pyridones and 4-Quinolones by Using (R,R)-1,2-bis(tert-butylsulfinyl)benzene as Ligand”Eur. J. Org. Chem.2011, 1443.(14) Fuzhong Han, Jun Chen, Xiangyang Zhang, Jibing Liu, Linfeng Cun, Jin Zhu, Jingen Deng, and Jian Liao* “Rhodium-catalyzed asymmetric addition of arylboronic acids toγ-phthalimido-substituted-α,β-unsaturated carboxylic acid esters: an approach toγ-amino acids”Tetrahedron Lett.2011,52, 830.(13) Jun Chen, Junmin Chen, Feng Lang, Xiangyang Zhang, Linfeng Cun, Jin Zhu, Jingen Deng and Jian Liao* “AC2-Symmetric Chiral Bis-Sulfoxide Ligand in Rhodium-Catalyzed Reaction: Asymmetric 1, 4- Addition of Sodium Tetraarylborates to Chromenones”J. Am. Chem. Soc.2010,132，4552. (Highlight bySynfacts,2010, 790.)(12) Feng Lang, Dong Li, Junmin Chen, Jun Chen, Liangchun Li, Linfeng Cun, Jin Zhu, Jingen Deng and Jian Liao* “tert-Butanesulfinylphosphines: Simple Chiral Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acid to Electron-Deficient olefins”Adv. Synth & Catal.2010,352, 843. ( Highlight bySynfacts,2010, 667)(11) 廖建，鄧金根 《不對(duì)稱(chēng)催化新概念與新方法》，（丁奎嶺、范青華主編）第20章：不對(duì)稱(chēng)催化—從學(xué)術(shù)研究到工業(yè)應(yīng)用（典型案例分析）。2009年，化學(xué)工業(yè)出版社。(10) Peng Wang,Junmin Chen,Linfeng Cun,Jingen Deng,Jin Zhuand Jian Liao* “Aryltert-Butyl Sulfoxide-Promoted Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes”O(jiān)rg. Biomol. Chem.,2009,7, 3741.(9) Xiaoyu Guan, Zhangqin Liu, Haoxi Huang, Liping Yang, Jian Liao* and Wenhao Hu* “Novel Cu2013S Bond Formation Through au2019,b-Elimination oftert-Butyl Sulfoxonium Ylides: A Facile Approach to Chiral Sulfoxides”Synlett.2009, 2183. （與華東師大胡文浩教授合作）(8) Junmin Chen, Feng Lang, Dong Li, Linfeng Cun, Jin Zhu, Jingen Deng, Jian Liao* “Palladium-catalyzed asymmetric allylic nucleophilic substitution reactions using chiraltert-butanesulfinylphosphine ligands”Tetrahedron: Asymmetry2009,20, 1953.(Highlight bySynfact,2009, 1374).(7) Dong Li, Jingen Deng, Jin Zhu, Jian Liao* “Synthesis of 3,3’-Substituted Biphenyl and Binaphthyl-based Phosphoramidite Ligands”Chin. Synth. Chem.2008,16, 656.(6) Junmin Chen, Dong Li, Haifeng Ma, Linfeng Cun, Jin Zhu, Jingen Deng, Jian Liao* “Catalytic asymmetric synthesis of α- branched chiral amines using a novel chiraltert-butanesulfinylphosphine ligand”Tetrahedron Lett.2008.49. 6921.(5) P. Harshad; J. Liao; R. Hedden* “Smectic Ordering in Main-Chain Siloxane Polymers and Elastomers Containingp-Phenylene Terephthalate Mesogens”Macromolecules2007,40, 6206.(4) J. Liao; Qing Wang * “Ruthenium-Catalyzed Knoevenagel Condensation: A New Route toward Cyano-Substituted Poly(p-phenylenevinylene)s”Macromolecules2004, 37, 7061.(3) J. Liao; X. X. Sun; X. Cui; K. B. Yu; J. Zhu; J. G. Deng* “Facile optical resolution of tert-butanethiosulfinate by molecular complexation with (R)-BINOL and study of chiral discrimination of the diastereomeric complexes”Chem. Eur. J.2003,9, 2611.(2) J. Liao; X. H. Peng; J. H. Zhang; K. B. Yu; X. Cui; J. Zhu; J. G. Deng* “Facile resolution of racemic terbutaline and a study of molecular recognition through chiral supramolecules based on enantiodifferentiating self-assembly”O(jiān)rg. & Biomol. Chem.2003,1, 1080.(1) J. H. Zhang, J. Liao, X. Cui, K. B. Yu, J. Zhu, J. G. Deng*, S. F. Zhu, L. X. Wang, Q. L. Zhou*, L. W. Chung, T. Ye* “Highly Efficient and practical resolution of 1,1u2019-spirobiindane-7,7u2019-diol by inclusion crystallization with N-benzylcinchonidinium chloride”Tetrahedron: Asymmetry2002,13, 1363.科研項(xiàng)目
國(guó)家自然科學(xué)基金委面上項(xiàng)目4項(xiàng)參加國(guó)家973計(jì)劃子項(xiàng)目1項(xiàng)中科院“西部之光”人才計(jì)劃1項(xiàng)四川省“百人計(jì)劃”1項(xiàng)
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