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  • 朱玉雷

    朱玉雷

    朱玉雷,男,出生于1964年9月,中科院山西煤化所煤轉(zhuǎn)化國家重點(diǎn)實(shí)驗(yàn)室與合成油品工程研究中心研究員。


    山西煤炭化學(xué)所研究員(博導(dǎo))

    ? 朱玉雷,男, 1964年9月生。1987年畢業(yè)于安徽師范大學(xué)化學(xué)系,獲理學(xué)學(xué)士。1988-2005年,在中國科學(xué)院山西煤炭化學(xué)研究所學(xué)習(xí)、工作,獲得理學(xué)碩士及理學(xué)博士學(xué)位;期間獲得中科院院長獎學(xué)金優(yōu)秀獎和中科院優(yōu)秀博士學(xué)位論文獎。2005年12月和2007年2月,作為高級訪問學(xué)者赴澳大利亞Monash大學(xué)綠色化學(xué)研究中心進(jìn)行技術(shù)交流。

    研究領(lǐng)域?yàn)榫?xì)化學(xué)品和可再生能源的多相催化反應(yīng)研究,解決了加氫、脫氫、氧化和耦合反應(yīng)過程中的關(guān)鍵工藝問題,相關(guān)新型技術(shù)成功地應(yīng)用于企業(yè)。作為項(xiàng)目負(fù)責(zé)人和研究骨干完成了多項(xiàng)國家基金、863和973項(xiàng)目。獲得2005年國家技術(shù)發(fā)明二等獎(第一完成人),2004年中國石化協(xié)會技術(shù)發(fā)明一等獎(第二完成人),2005年中國科學(xué)院杰出科技成就獎(集體),2006年獲國務(wù)院特殊專家津貼;2007年被評選為中共山西省委聯(lián)系的高級專家,2012年度山西省科技奉獻(xiàn)獎(先進(jìn)個人特等獎),2013年度 “山西省五一勞動獎?wù)隆保?013年度獲山西省科學(xué)技術(shù)獎/自然科學(xué)類/二等(第一完成人)獎勵和表彰。作為第一作者和通訊聯(lián)系人,相關(guān)基礎(chǔ)研究結(jié)果在ACS Catal., Chem. Commun., J. Catal., Green Chem.等專業(yè)刊物上發(fā)表論文100多篇。專利20余項(xiàng);指導(dǎo)畢業(yè)博士25名,碩士15名;目前在培養(yǎng)博士生5名,碩士生1名。

    研究領(lǐng)域

    ?主要從事醛酮、酸酐類催化加氫及二醇脫氫轉(zhuǎn)化為精細(xì)化學(xué)品,及相關(guān)催化劑與反應(yīng)過程的實(shí)驗(yàn)和基礎(chǔ)研究。在不同尺度上對催化劑結(jié)構(gòu)、表面酸堿性質(zhì)與催化性能的內(nèi)在聯(lián)系、和反應(yīng)耦合促進(jìn)化學(xué)反應(yīng)的本質(zhì)等進(jìn)行了研究與實(shí)踐探索,深化了對促進(jìn)化學(xué)反應(yīng)和反應(yīng)耦合作用本質(zhì)的認(rèn)識。為糖類衍生物合成精細(xì)化學(xué)品工業(yè)過程開發(fā)提供關(guān)鍵的催化劑技術(shù)基礎(chǔ)。

    獲獎及榮譽(yù)

    ?2005年度“耦合法生產(chǎn)γ-丁內(nèi)酯技術(shù)”項(xiàng)目獲得國家技術(shù)發(fā)明二等獎(第1完成人),作為技術(shù)骨干承擔(dān)的“漿態(tài)床煤基合成油工業(yè)化技術(shù)”項(xiàng)目獲中國科學(xué)院杰出科技成就獎; 2004年獲中國石化協(xié)會技術(shù)發(fā)明一等獎(第2完成人),山西省技術(shù)發(fā)明二等獎(第2完成人);2013年山西省自然科學(xué)二等獎 (第1完成人);及2006年度獲得國務(wù)院特殊專家津貼等。

    代表論著

    [1] Yu-Lei Zhu, Hong-Wei Xiang, Gui-Sheng Wu, Liang Bai, Yong-Wang Li, A novel route for synthesis of γ-butyrolactone through the coupling of hydrogenation and dehydrogenation, Chem. Commun., 2002,3:254-255.

    [2] Yu-Lei Zhu, Hong-Wei Xiang , Yong-Wang Li, Haijun Jiao, Gui-Sheng Wu, Bing Zhong, Guang-Qing Guo; New strategy for the efficient synthesis of 2-methylfuran and γ-butyrolactone, New J. Chem., 2003, 27:208-210.

    [3] Yu-Lei Zhu*, Gang-Wei Zhao, Jie Chang, Jun Yang, Hong-Yan Zheng, Hong-Wei Xiang, Yong-Wang Li, New insight for reaction route of hydrogenation of maleic anhydride to γ-butyrolactone, Catal. Lett., 2004, 96(3-4):123-127.

    朱玉雷

    [4] Yu-Lei Zhu, Jun Yang, Gen-Quan Dong, Hong-Yan Zheng, Hao-Hong Zhang, Hong-Wei Xiang, Yong-Wang Li, An environmentally benign route to γ-butyrolactone through the coupling of hydrogenation and dehydrogenation, Appl. Catal. B: Environmental, 2005, 57(3):183-190.

    [5] Yulei Zhu, Jim Patel, Selma Mujcinovic, W. Roy Jackson and Andrea J. Robinson, Preparation of terminal oxygenates from renewable natural oils by a onepot metathesis- isomerisationu2013methoxycarbonylationu2013transesterification reaction sequence, Green Chem., 2006, 8: 746u2013749.

    [6] Hong-Yan Zheng, Yu-Lei Zhu*, Zong-Qing Bai, Long Huang, Hong-Wei Xiang, Yong-Wang Li, An environmentally benign process for the efficient synthesis of cyclohexanone and 2-methylfuran; Green Chem., 2006, 8:107-109.

    [7] Long Huang, Yulei Zhu*, Hongyan Zheng, Mingxian Du, Yongwang Li, Vapor-phase hydrogenolysis of biomass-derived lactate to 1,2-propanediol over supported metal catalysts, Appl. Catal. A: General, 2008, 349(2):204-211.

    [8] Long Huang, Yulei Zhu?, Chunfang Huo, Hongyan Zheng, Gang Feng, Chenghua Zhang, Yongwang Li, Mechanistic insight into the heterogeneous catalytic transfer hydrogenation over Cu/Al2O3: Direct evidence for the assistant role of support, J. Mol. Catal. A: General, 2008, 288(1-2):109-115.

    [9] Guoqiang Ding, Yulei Zhu*, Hongyan Zheng, Wei Zhang, Yongwang Li, Study on the reaction pathway in the vaporphase hydrogenation of biomass-derived diethyl succinate over CuO/ZnO catalyst, Catal. Commun., 2010, 11(14):1120-1124.

    [10] Xiaoyuan Liao, Yulei Zhu*, Sheng-Guang Wang, Hongmei Chen, Yongwang Li, Theoretical elucidation of acetylating glycerol with acetic acid and acetic anhydride, Appl. Catal. B: Environmental, 2010, 94 (1-2): 64-70.

    [11] Wei Zhang, Yulei Zhu*, Shasha Niu, Yongwang Li,A study of furfural decarbonylation on K-doped Pd/Al2O3 catalysts, J. Mol. Catal. A: Chemical, 2011, 335(1-2):71u201381.

    [12] Shanhui Zhu, Yulei Zhu*, Shunli Hao, Hongyan Zheng, Tao Mo and Yongwang Li, One-step hydrogenolysis of glycerol to biopropanols over Ptu2013H4SiW12O40/ZrO2 catalysts, Green Chem., 2012, 14:2607u20132616.

    [13] Tiansheng Deng, Xiaojing Cui, Yongqin Qi, Yinxiong Wang, Xianglin Hou, Yulei Zhu*, Conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by ZnCl2 in water, Chem. Commun., 2012, 48 (44):5494 u2013 5496.

    [14] Lungang Chen, Yulei Zhu*, Hongyan Zheng, Chenghua Zhang, Yongwang Li, Aqueous-phase hydrodeoxygenation of propanoic acid over the Ru/ZrO2 and Ru-Mo/ZrO2 catalysts, Appl. Catal. A: General, 2012,411?412:95?104.

    [15] Bin Zhang, Yulei Zhu*, Guoqiang Ding, Hongyan Zheng, Yongwang Li, Modification of the supported Cu/SiO2 catalyst by alkaline earth metals in the selective conversion of 1,4-butanediol to γ-butyrolactone, Appl. Catal. A: General, 2012, 443?444:191-201.

    [16] Bin Zhang, Yulei Zhu*, Guoqiang Ding, Hongyan Zheng, Yongwang Li, Selective conversion of furfuryl alcohol to 1,2-pentanediol over a Ru/MnOx catalyst in aqueous phase, Green Chem., 2012, 13:3402-3409.

    [17] Shanhui Zhu, Yanan Qiu, Yulei Zhu*, Shunli Hao, Hongyan Zheng, Yongwang Li, Hydrogenolysis of glycerol to 1,3-propanediol over bifunctional catalysts containing Pt and heteropolyacids, Catal. Today. 2013, 212:120-126.

    [18] Shanhui Zhu, Yulei Zhu*, Xiaoqing Gao, Tao Mo, Yifeng Zhu, Yongwang Li, Production of bioadditives from glycerol esterification over zirconia supported heteropolyacids, Bioresour. Technol., 2013, 130(8):45-51.

    [19] Shanhui Zhu, Xiaoqing Gao, Yulei Zhu*, Yifeng Zhu, Hongyan Zheng, Yongwang Li, Promoting effect of boron oxide on Cu/SiO2 catalyst for glycerol hydrogenolysis to 1,2-propanediol, J. Catal., 2013, 303:70-79.

    [20] Shanhui Zhu, Xiaoqing Gao, Yulei Zhu*, Yifeng Zhu, Xiaomin Xiang, Caixia Hu, Yongwang Li, Alkaline metals modified Ptu2013H4SiW12O40/ZrO2 catalysts for the selective hydrogenolysis of glycerol to 1,3-propanediol, Appl. Catal. B: Environmental, 2013, 140-141: 60-67.

    [21] Shanhui Zhu, Xiaoqing Gao, Fang Dong, Yulei Zhu*, Hongyan Zheng, Yongwang Li, Design of a highly active silver exchanged phosphotungstic acid catalyst for glycerol esterification with acetic acid, J. Catal., 2013, 306:155-163.

    [22] Yifeng Zhu, Yulei Zhu*, Guoqiang Ding, Shanhui Zhu, Hongyan Zheng, Yongwang Li, Highly selective synthesis of ethylene glycol and ethanol via hydrogenation of dimethyl oxalate on Cu catalyst: influence of support, Appl. Catal. A: General, 2013,468: 296-304.

    [23] Hongliang Wang, Tiansheng Deng, Yingxiong Wang, Yongqin Qi, Xianglin Hou, Yulei Zhu*, Efficient catalytic system for the conversion of fructose into 5-ethoxymethylfurfural, Bioresour. Technol., 2013, 136:394-400.

    [24] Hongliang Wang, Tiansheng Deng, Yingxiong Wang, Xiaojing Cui, Yongqin Qi, Xindong Mu, Xianglin Hou and Yulei Zhu*, Graphene oxide as a facile acid catalyst for the one-pot conversion of carbohydrates into 5-ethoxymethylfurfural, Green Chem., 2013, 15: 2379 u20132383.

    [25] Bin Zhang, Guoqiang Ding, Hongyan Zheng, Yulei Zhu*, Transesteri?cation of dimethyl carbonate with tetrahydrofurfuryl alcohol on the K2CO3/ZrO2 catalyst—Function of the surface carboxylate species, Appl. Catal. B: Environmental, , 2014,152-153: 226u2013232.

    [26] Hongliang Wang, Qingqiang Kong, Yingxiong Wang, Tiansheng Deng, Chengmeng Chen, Xianglin Hou and Yulei Zhu*, Graphene Oxide Catalyzed Dehydration of Fructose into 5-Hydroxymethylfurfural with Isopropanol as Cosolvent, ChemCatChem, 2014, 6(3): 728u2013732.

    [27] Yifeng Zhu, Xiao Kong, Dong-Bo Cao, Jinglei Cui, Yulei Zhu*, and Yong-Wang Li. The rise of calcination temperature enhances the performance of Cu catalysts: contributions of support, ACS Catal., 2014, 4(10): 3675-3681

    [28] Yifeng Zhu, Xiao Kong, Xianqing Li, Guoqiang Ding, Yulei Zhu*, and Yong-Wang Li, Cu nanoparticles inlaid mesoporous Al2O3 as a high-performance bifunctional catalyst for ethanol synthesis via dimethyl oxalate hydrogenation, ACS Catal., 2014, 4(10): 3612-3620

    [29] Shanhui Zhu, Xiaoqing Gao, Yulei Zhu*, Jinglei Cui, Hongyan Zheng, Yongwang Li, SiO2 promoted Pt-WOx/ZrO2 catalysts for the selective hydrogenolysis of glycerol to 1,3-propanediol, Appl. Catal. B, 2014, 158u2013159: 391-399.

    [30] Chengwei Liu, Chenghua Zhang, Jian Xu, Yulei Zhu*. Effect of WOX on Bifunctional Pd-WOX/A12O3 Catalysts for the selective hydrogenolysis of glucose to 1,2-Propanediol, ACS Catal., 2015, 5: 4612-4623.

    [31] Jinglei Cui, Jingjing Tan, Yulei Zhu* and Yongwang Li. Direct conversion of carbohydrates to γ-valerolactone facilitated by a solvent effect, Green Chem., 2015, 17: 3084-3089.

    [32] Jingjing Tan, Jinglei Cui, Guoqiang Ding, Yulei Zhu*, Yongwang Li. Water-Promoted Hydrogenation of Levulinic Acid to γ-Valerolactone on Supported Ruthenium Catalyst, ChemCatChem, 2015, 7(3): 508-512

    [33] Fang Dong, Yulei Zhu,* Guoqiang Ding, Jinglei Cui, Xianqing Li, Yongwang Li. One-step conversion of furfural into 2-methyltetrahydrofuran under mild conditions, ChemSusChem, 2015, 8: 1534-1537.

    [34] Xiao Kong, Yifeng Zhu, Guoqiang Ding, Yulei Zhu* and Yong-Wang Li. Rational design of Ni-based catalysts derived from hydrotalcite for selective hydrogenation of 5-hydroxymethylfurfural, Green Chem., 2015, 17: 2504-2514.

    [35] Xiao Kong, Yifeng Zhu, Hongyan Zheng, Xianqing Li, Yulei Zhu*, and Yong-Wang Li. Ni Nanoparticles Inlaid Nickel Phyllosilicate as a Metal-Acid Bifunctional Catalyst for Low-Temperature Hydrogenolysis Reactions, ACS Catal., 2015, 5(10): 5914-5920

    [36] Yifeng Zhu, Xiao Kong, Yulei Zhu*, Yong-Wang Li. Construction of Cu/ZrO2/A12O3 composites for ethanol synthesis: Synergies of ternary sites for cascade reaction, Appl. Catal. B, 2015, 166-167: 551-559.

    [37] Jinglei Cui, Jingjing Tan, Yulei Zhu*, Yongwang Li. Conversion of xylose to furfuryl alcohol and 2-methylfuran in a continuous fix-bed reactor, ChemSusChem, 2016, 9:1259-1262.

    [38] Jinglei Cui, Jingjing Tan, Yulei Zhu*, Yongwang Li. Conversion of carbohydrates to furfural via selective cleavage of carbon-carbon bond: cooperative effect of zeolite and solvent, Green Chem., 2016, 18: 1619-1624.

    承擔(dān)科研項(xiàng)目情況

    1.承擔(dān)國家科技部973“糖類衍生物催化制含氧燃料的基礎(chǔ)研究”項(xiàng)目(2012CB215305)

    2.國家科技部和中科院等聯(lián)合重大項(xiàng)目漿態(tài)床煤基合成液體燃料工業(yè)技術(shù)開發(fā)中的化學(xué)品研究及應(yīng)用

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