個人簡介
2007年獲得理學博士學位，學位論文的研究集中于二價鈀的系列催化反應(yīng)；2007年至2010年于美國Akron大學高分子系Li Jia教授小組進行博士后研究。研究領(lǐng)域包括過渡金屬催化的小分子雜環(huán)化合物羰基化聚合，生成聚酰胺和聚酯。應(yīng)用高壓原位紅外研究了羰基化聚合反應(yīng)的機理，并優(yōu)化了N-烷基氮雜環(huán)丙烷的羰基化聚合反應(yīng)以及雙嵌段聚(b-二肽)的合成。在雙嵌段聚(b-二肽)的溶液自組裝研究中，與程正迪教授研究小組合作，應(yīng)用核磁共振，紅外光譜，差示掃描量熱法(DSC)，X-射線粉末衍射等技術(shù)來表征并確證了類-折疊中心的自組裝結(jié)構(gòu)。在聚(b-二肽)材料的抗蛋白質(zhì)吸附研究中，應(yīng)用表面等離子共振光譜(SPR)技術(shù)對一系列合成的材料進行了測試。結(jié)果表明這一系列材料對于非特異性蛋白質(zhì)有著非常優(yōu)秀的抗吸附能力。2010年底進入蘇州大學材化部潘勤敏老師團隊工作。
研究領(lǐng)域
烯烴聚合及雜環(huán)分子的羰基化聚合方法學研究
代表性論文
1. Shaohui Lin, Bo Zhang, Michael J. Skoumal, Brian Ramunno, Linyun Liu*, Xiaopeng Li, Chrys Wesdemiotis, Li Jia*; “Antifouling Poly(b-peptoid)s”, 2011, , 2573-2582.
2. Shaohui Lin, Xinfei Yu, Yingfeng Tu, Hongyu Xu, Stephen Z. D. Cheng*, Li Jia*; “Poly(a-alanoid- block-b-alanine)s: Synthesis via Cobalt-Catalyzed Carbonylative Polymerization and Self-Assembly”, 2010, , 4273-4275.
3. Shaohui Lin, Xiyan Lu*; “Cationic Palladium(II) with Bipyridine Ligand Catalyzed Addition of Arylboronic Acids to b,b-disubstituted enones. Construction of Quaternary Carbon Centers.” 2010, , 2536.
4. Shaohui Lin, Hongyu Xu, Nathalie LeGall, Jiquan Zhao, Li Jia*; “Synthesis of block poly(b-alanoid)s via cobalt-catalyzed carbonylative polymerization of N-alkylaziridines.” Abstracts of Papers, 236th ACS National Meeting, Philadelphia, PA, United States, August 17-21, 2008.
5. Shaohui Lin, Xiyan Lu*; “Cationic Palladium(II) with Bipyridine Ligand Catalyzed Addition of Arylboronic Acids to Aldehydes. One Pot Synthesis of Unsymmetrical Triarylmethanes.” 2007, , 9757-9760.
6. Shaohui Lin, Xiyan Lu*; “Palladium-Bipyridine Catalyzed Conjugate Addition of Arylboronic Acids to a,b-Unsaturated Carbonyl Compounds in Aqueous Media.” 2006, , 7167-7170.
7.Xiyan Lu*, Shaohui Lin; “Pd(II)-Bipyridine Catalyzed Conjugate Addition of Arylboronic Acid to a,b-Unsaturated Carbonyl Compounds.” 2005, , 9651-9653.
8.Shengming Ma*, Bukuo Ni, Shaohui Lin, Zhiqiang Liang; “Intramolecular Double or Triple Suzuki Coupling Reaction of Substituted Di- or Tribromobenzenes. An Easy Synthesis of Fused Tri- or Tetracycles with a Benzene Core.” 2005, , 5389-5395.
