基本信息
職 稱: 副研究員
學(xué) 歷: 博士研究生
通訊地址: 上海市零陵路345號(hào)
教育背景
1998年9月至2002年7月：南開大學(xué)化學(xué)學(xué)院獲得學(xué)士學(xué)位。2002年9月至2007年7月：中科院上海有機(jī)所金屬有機(jī)重點(diǎn)實(shí)驗(yàn)室攻讀博士學(xué)位，專業(yè)為理論有機(jī)化學(xué)，導(dǎo)師為丁奎嶺研究員
工作經(jīng)歷
2011年3月至今：中科院上海有機(jī)化學(xué)研究所金屬有機(jī)化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室麻生明組副研究員
2007年7月至2008年12月：中科院上海有機(jī)所金屬有機(jī)重點(diǎn)實(shí)驗(yàn)室丁奎嶺課題組，助理研究員
2009年1月2011年2月：美國(guó)北德克薩斯大學(xué)（University of North Texas）Professor Weston T. Borden 研究組從事博士后研究
研究方向
運(yùn)用電子結(jié)構(gòu)理論研究不同類型分子體系的化學(xué)反應(yīng)機(jī)理
專家類別：副研究員
代表論著
1.Xue Zhang, Ayan Datta, David A. Hrovat, and Weston Thatcher Borden*, “Calculations Predict Large Inverse Kinetic Isotope Effects on Tunneling by Carbon in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperatures”, J. Am. Chem. Soc.
2.Xue Zhang, David A. Hrovat, and Weston Thatcher Borden*, “Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures”, Org. Lett.
3.Xue Zhang, Srikanth Kandala, Li Yang, William H. Watson, Xiaoping Wang, David A. Hrovat, Weston Thatcher Borden,* and Michael G. Richmond*, “Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phospine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3(CO)10(dppbz), 1,1-Os3(CO)10(dppbzF4), HOs3(CO)9[μ-1,2-PhP (C6H4-η1)C6H4PPh2], and HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6F4PPh2]”, Organometallics
4.Xue Zhang, David A. Hrovat, Ayan Datta and Weston Thatcher Borden*, “Effects of Geminal Methyl Groups on the Tunnelling Rates in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperature”, Organic & Biomolecular Chemistry ASAP.
5.Xue Zhang, Haifeng Du, Zheng Wang, Yun-Dong Wu,* and Kuiling Ding*, “Experimental and Theoretical Studies on the Hydrogen-Bond-Promoted Enantioselective Hetero-Diels-Alder Reaction of Danishefskyu2019s Diene with Benzaldehyde”, J. Org. Chem
6.Ollie M. Gonzalez-James, Xue Zhang, Ayan Datta, David A. Hrovat, Weston Thatcher Borden*, and Daniel A. Singleton*, “Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular 12C/13C Kinetic Isotope Effects”, J. Am. Chem. Soc
7.Liu, Y.; Sandoval, C. A.; Yamaguchi, Y.; Zhang, X.; Wang, Z.; Kato, K.; Ding, K*., “Hydrogen Bonding Makes a Difference in the Rhodium-Catalyzed Enantioselective Hydrogenation Using Monodentate Phosphoramidites”, J. Am. Chem. Soc.
8.Qing Jing, Xue Zhang, Jie Sun, Kuiling Ding*, “Bulky Achiral Triarylphosphines Mimic BINAP in Ru(II)-Catalyzed Asymmetric Hydrogenation of Ketones”, Adv. Synth. Catal
9.Haifeng Du, Xue Zhang, Zheng Wang, and Kuiling Ding*, “One catalyst for two distinct reactions: sequential asymmetric hetero Diels-Alder reaction and diethylzinc”, Tetrahedron
10.Wen, YQ; Song, YL; Zhao, DB; Ding, KL; Bian, J; Zhang, X; Wang, JX; Liu, Y; Jiang, L; Zhu, DB, “Highly regio- and enantioselective thermal [2+2] cycloaddition of coumarin in a crystalline inclusion complex under high vacuum”, Chem. Commun.
11.Yu Yuan, Xue Zhang, and Kuiling Ding*, “Quasi solvent-free enantioselective carbonyl-ene reaction with extremely low catalyst loading”, Angew. Chem. Int. Ed.