聚合物納米結(jié)構(gòu)材料：

1、聚合物納米結(jié)構(gòu)材料的構(gòu)筑及其光電特性；

2、基于聚合物納米纖維復(fù)合材料的功能特性；

3、用于智能服裝的信息纖維材料。

(1) 具有核殼結(jié)構(gòu)的導(dǎo)電高分子、金屬氧化物與碳納米管復(fù)合體系的研究。特別注重高有序納米結(jié)構(gòu)和功能特性的調(diào)控和多功能集成。該復(fù)合體系在超級(jí)電容器、太陽(yáng)能電池、光電納米器件、傳感器等方面具有潛在的應(yīng)用前景。就聚苯胺/碳納米管復(fù)合體系，作為超級(jí)電容器儲(chǔ)能材料，其最大比電容量可達(dá)560F/g。具有核殼結(jié)構(gòu)復(fù)合體系的綜合性能明顯優(yōu)異。

(2) 高彈高導(dǎo)的導(dǎo)電纖維的研究。這種新型導(dǎo)電纖維除了新賦予的優(yōu)異的導(dǎo)電性能以外，還保留著有機(jī)纖維基體原有的力學(xué)性能，特別是纖維的柔順性和可編織性，可通過(guò)針織、機(jī)織編織成織物。這種導(dǎo)電纖維與織物除了具備傳統(tǒng)的抗靜電與電磁屏蔽功能特性外，還可用來(lái)制作纖維應(yīng)力傳感、氣體傳感、液體傳感、光、熱傳感等多重響應(yīng)傳感器，并在金屬離子吸附、催化去污和能量存儲(chǔ)以及軍事偽裝等領(lǐng)域顯示出巨大的應(yīng)用潛力。如聚氨酯基的柔性導(dǎo)電纖維的電導(dǎo)率比常見(jiàn)的抗靜電纖維高4～7個(gè)數(shù)量級(jí)。

(3) 生物可降解的固-固相變納米纖維材料的研究。通過(guò)一種綠色途徑將儲(chǔ)能單元接枝到剛性骨架上，開(kāi)發(fā)出一種新型生物可降解的納米纖維儲(chǔ)能材料，具有儲(chǔ)能性能高與結(jié)構(gòu)穩(wěn)定的優(yōu)點(diǎn)，在溫度調(diào)節(jié)及蓄熱保溫等領(lǐng)域有著廣泛的應(yīng)用前景。

2000年獲得中科院院長(zhǎng)獎(jiǎng)學(xué)金優(yōu)秀獎(jiǎng)

主持承擔(dān)了上海市科委浦江人才計(jì)劃“基于導(dǎo)電高分子納米纖維網(wǎng)絡(luò)的光伏材料設(shè)計(jì)及智能服裝柔性能源的研發(fā)”，上海市科委“創(chuàng)新行動(dòng)計(jì)劃”項(xiàng)目重大基礎(chǔ)項(xiàng)目子課題“高性能PANCF紡絲原液熱力學(xué)及流變行為研究”，上海市科委重點(diǎn)基礎(chǔ)項(xiàng)目“自增強(qiáng)型資源可再生生物聚酯纖維的化學(xué)設(shè)計(jì)與梯度結(jié)構(gòu)調(diào)控”和教育部高等學(xué)�？萍紕�(chuàng)新工程重大項(xiàng)目培育資金“電子信息纖維材料及其智能服裝的工程化研究”等項(xiàng)目。

主持過(guò)一項(xiàng)國(guó)家自然科學(xué)基金項(xiàng)目(功能化的聚酰亞胺激光消融材料的研究，批準(zhǔn)號(hào)29604006)和一項(xiàng)國(guó)家博士后基金，作為主要研究骨干參加過(guò)四項(xiàng)國(guó)家自然科學(xué)基金項(xiàng)目，一項(xiàng)國(guó)家杰出青年基金，一項(xiàng)"十五"國(guó)家科技攻關(guān)項(xiàng)目的子課題和一項(xiàng)中科院院重點(diǎn)基金的研究項(xiàng)目。

研究論文：

[1] Yuanyu Chen,Zongyi Qin, Guofeng Tang, Lijun Wei, Houlin Du, and Weiping Du, Balancing Optical Property and Enhancing Stability for High-Refractive Index Polythiourethane with Assistance of Cubic Thiol-Functionalized Silsesquioxanes, ACS Applied Polymer Materials20213(1), 153-161

[2] Li, Tao & Ding, Bing & Malgras, Victor & Na, Jongbeom &Qin, Zongyi& Lu, Xiangjun & Bando, Yoshio & Nara, Hiroki & Alothman, Zeid & Wang, Jie & Yamauchi, Yusuke. (2020). Hollow carbon architectures with mesoporous shells via self-sacrificial templating strategy using metal-organic frameworks. Chemical Engineering Journal. 127635. 10.1016/j.cej.2020.127635.

[3] Zeng, Fanxin &Qin, Zongyi& Li, Tao & Chen, Yuanyu & Yang, Lifeng. (2020). Boosting phosphorusu2013nitrogenu2013silicon synergism through introducing graphene nanobrick wall structure for fabricating multifunctional cotton fabric by spray assisted layer-by-layer assembly. Cellulose. 27. 10.1007/s10570-020-03235-1.

[4] Shen, Yueying &Qin, Zongyi& Li, Tao & Zeng, Fanxin & Chen, Yuanyu & Liu, Na. (2020). Boosting the supercapacitor performance of polyaniline nanofibers through sulfonic acid assisted oligomer assembly during seeding polymerization process. Electrochimica Acta. 356. 136841. 10.1016/j.electacta.2020.136841.

[5] Dou, Zhenjun & Zhou, Yi & Shen, Yueying & Xu, Xian & Hu, Shuo & Yang, Lifeng & Qin, Zongyi. (2020). Realizing ultrahigh areal capacitance and cycle stability of polyaniline nanofiber network grown on grapheneu2013modified carbon cloth with the addition of trivalent iron ions in electrolyte. Electrochimica Acta. 351. 136448. 10.1016/j.electacta.2020.136448.

[6] Li, Tao & Ding, Bing & Wang, Jie & Qin, Zongyi & Fernando, Joseph & Bando, Yoshio & Nanjundan, Ashok Kumar & Kaneti, Yusuf & Golberg, Dmitri & Yamauchi, Yusuke. (2020). Sandwich-Structured Ordered Mesoporous Polydopamine/MXene Hybrids as High-Performance Anodes for Lithium-Ion Batteries. ACS Applied Materials & Interfaces. 12. 10.1021/acsami.9b18883.

[7] Hu, Shuo & Ding, Lei & Shen, Yueying & Dou, Zhenjun & Yang, Lifeng & Xu, Xian & Qin, Zongyi. (2020). Promoting Oriented Growth of Polyaniline Array on Carbon Cloth through In Situ Chemical Polymerization under High Voltage Electric Field for Flexible Supercapacitor with High Areal Capacity and Stability. ACS Applied Energy Materials. XXXX. 10.1021/acsaem.9b02398.

[8] Dou, Zhenjun & Qin, Zongyi & Shen, Yueying & Hu, Shuo & Liu, Na & Zhang, Youwei. (2019). Highu2013performance flexible supercapacitor based on carbon cloth through inu2013situ electrochemical exfoliation and reu2013deposition in neutral electrolyte. Carbon. 153. 617-624. 10.1016/j.carbon.2019.07.073.

[9] Shen, Yueying & Qin, Zongyi & Hu, Shuo & Yang, Lifeng & Xu, Xian & Ding, Lei & Zhang, Youwei. (2019). In situ hybridization of graphene sheets onto polyaniline nanofiber arrays grown on the surface of carbon cloth under high electric voltage field for highu2013performance flexible supercapacitor. Carbon. 158. 10.1016/j.carbon.2019.11.045.

[10] Ding, Lei & Qin, Zongyi & Dou, Zhenjun & Shen, Yueying & Cai, Yameng & Zhang, Youwei & Zhou, Yi. (2018). Morphology-promoted synergistic effects on the sensing properties of polyaniline ultrathin layers on reduced graphene oxide sheets for ammonia and formaldehyde detection. Journal of Materials Science. 53. 10.1007/s10853-018-2109-7.

[11] Yi Zhou, Zong-Yi Qin, Li Li, Yu Zhang, Yu-Ling Wei, Ling-Feng Wang, Mei-Fang Zhu, Polyaniline/multi-walled carbon nanotube composites with coreu2013shell structures as supercapacitor electrode materials, Electrochimica Acta 55: 3904u20133908 (2010)

[12] Li Li, Zong-Yi Qin, Ling-Feng Wang, Hong-Jin Liu, Mei-Fang Zhu, Anchoring alpha-manganese oxide nanocrystallites on multi-walled carbon nanotubes as electrode materials for supercapacitor, J Nanopart Res 12: 2349u20132353 (2010)

[13] Qing-Qing Fan, Zong-Yi Qin, Xia Liang, Li Li, Wen-Hua Wu, Mei-Fang Zhu, Reducing defects on multi-walled carbon nanotube surfaces induced by low-power ultrasonic-assisted hydrochloric acid treatment, Journal of Experimental Nanoscience, 5(4): 337u2013347 (2010)

[14] Guangzhao Zhai, Qingqing Fan, Yue Tang, Yu Zhang, Ding Pan, Zongyi Qin. Conductive composite films composed of polyaniline thin layers on microporous polyacrylonitrile surfaces. Thin Solid Films 519: 169u2013173 (2010)

[15] L. Li, Zong-Yi QIN, X. Liang, Q. Fan, Y. Lu, W. Wu, M. Zhu, Facile Fabrication of Uniform Core-Shell Structured Carbon Nanotube-Polyaniline Nanocomposites, J. Phys. Chem. C. 113: 5502u20135507 (2009)

[16] Q. Liu, M. Zhu, W. Wu, Zong-Yi QIN, Reducing the formation of six-membered ring ester during thermal degradation of biodegradable PHBV to enhance its thermal stability, Polym. Degrad. Stab. 94: 18u201324 (2009)

[17] L. Li, Zong-Yi QIN, Q. Fan, Y. Lu, M. Zhu, Y. Ding, Performance of hydrothermal fabricated manganese dioxide CNTs nanocomposites as electrodes material, Journal of Scientific Conference Proceedings, 1: 1u20134 (2009)

[18] Y. Jiang, M. Zhu, B. Li, Y. Liu, Zong-Yi QIN, L. Chen, Y. Chen, Swelling Behavior of Poly(acrylamide)/Clay Nanocomposite Hydrogels in Acrylamide Aqueous Solution, J. Appl. Polym. Sci., 112: 353u2013358 (2009)

[19] K.P. Shiu, Zong-Yi QIN, Z. Yang, Relaxation times and energy barriers of rubbing-induced birefringence in glass-forming polymers, Eur. Phys. J. E. 27: 413u2013420 (2008)

[20] C.C. Wong, Zong-Yi QIN, Z. Yang, The absence of physical-aging effects on the surface relaxations of rubbed polystyrene, Eur. Phys. J. E. 25: 291u2013298 (2008)

[21] C. Ma, W. Du, H. Chen, Z. Liu, Zong-Yi QIN, D. Pan, Influences of Nonsolvent and Temperature on Critical Viscoelastic Behaviors of Ternary Polyacrylonitrile Solutions Around the Sol-Gel Threshold, J. Polym. Sci. Part B: Polym. Phys. 46: 2637u20132643 (2008)

[22] C. Ma, W. Yan, L. Zhang, Zong-Yi QIN, P. Ding, Rheological behavior during thermotropic gelation of polyacrylonitrile concentrated solutions, J. Cent. South Univ. Technol. 15(s1): 122-125 (2008)

會(huì)議論文：

[1] Y Zhang, X Ren, K Zhang, Zong-Yi QIN, Influence of shell layer thickness on electrochemical process for polyaniline and polypyrrole coaxial nanofibers as supercapacitor electrode materials, The 9th China International Nanoscience and Technology Symposium, 2010, Xi’an.

[2] HY Yu, Z Zhou, SS Shan, N. Guo, MF Zhu, Zong-Yi QIN. Electrospun solid-solid phase change nanofibers of poly(ethylene glycol) grafted onto the surface of cellulose nanocrystals. The 9th China International Nanoscience and Technology Symposium, 2010, Xi’an.

[3] Z Zhou, HY Yu, Zong-Yi QIN. Study on the Preparation and Properties of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(PHBV)/Microcrystalline Cellulose and PHBV/Cellulose Nanocrystal Composites. The 9th China International Nanoscience and Technology Symposium, 2010, Xi’an.

[4] 范青青，張曉琳，丁永生，秦宗益，新型聚氨酯基導(dǎo)電纖維與織物研制及應(yīng)用探討，第十一屆新型化纖原料在針織及其他相關(guān)行業(yè)應(yīng)用技術(shù)研討會(huì)，2010，鄭州。

[5] Q Fan, Zong-Yi Qin, L Chen, J Gong, Y Tang, M Zhu, Preparation and sensing properties of novel polyurethane-carbon nanotube composite fibers, 10th European Symposium on Polymer Blends, 2010, Dresden, Germany.

[6] L. Wang, Zong-Yi QIN, L. Li, Y. Zhang, M. Zhu, Novel ternary composite consisting of multi-wallled carbon nanotubes and manganese dioxide nanorods dispersed in polyaniline matrix as supercapacitve material, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.

[7] Y. Zhou, Zong-Yi QIN, H. Liu, Y. Wei, L. LI, M. Zhu, Conductive Polymer/ Carbon Nanotubes Nanocomposites with Core-Shell Structures: Preparation and Properties, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.

[8] Y. Zhang, Zong-Yi QIN, Y. Wei, Y. Zhou, J. Ni, M. Zhu, Core-shell Nanostructured Polyaniline/Polypyrrole Composites as Electrode Materials for Supercapacitors, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.

[9] Q. Fan, Zong-Yi QIN, C. Zhao, J. Gong, M. Zhu, L. Li, Y. Ding, Evaluation temperature and strain sensing properties of electrically conductive elastic fibres, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.

[10] H. Liu, Zong-Yi QIN, Y. Zhou, L. Li, M. Zhu, Effect of Core-Shell Heterostructure on the Optical and Electrochemical Properties for Poly(p-phenylenevinylene) Wrapped Multi-walled Carbon Nanotubes, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.

[11] G. Zhai, Zong-Yi QIN, H. Li, H. Chen, D. Pan, Flexible conducting polyaniline/polyacrylonitrile composite films, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.

[12] L. Li, Zong-Yi Qin, Q. Fan, Y. Lu, M. Zhu, Y. Ding, Performance of hydrothermal fabricated manganese dioxide CNTs nanocomposites as electrodes material, 7th China international conference on nanoscience and technology, 2008，Wuhan, China

[13] 范青青，秦宗益，朱美芳，李龍飛，丁永生，高電導(dǎo)與高彈性碳納米管表面復(fù)合聚氨酯導(dǎo)電纖維，2008 年上海納米科技與產(chǎn)業(yè)發(fā)展研討會(huì)，上海.

[14] 周毅，秦宗益，朱美芳，聚苯胺/多壁碳納米管核殼結(jié)構(gòu)中的聚苯胺摻雜效應(yīng)，2008 年上海納米科技與產(chǎn)業(yè)發(fā)展研討會(huì)，上海。

[15] 王凌鳳，秦宗益，李立，朱美芳，采用水熱法合成MnO2納米棒/多壁納米管復(fù)合材料及其超電容特性研究, 2008 年上海納米科技與產(chǎn)業(yè)發(fā)展研討會(huì)，上海。

[16] 魏玉玲，秦宗益，陸亞清，朱美芳，界面聚合制備聚苯胺納米纖維，2008 年上海納米科技與產(chǎn)業(yè)發(fā)展研討會(huì)，上海。

[16] 鈕曉鳴，放大看納米――2008 年上海納米科技與產(chǎn)業(yè)發(fā)展研討會(huì)論文選, 魏玉玲，秦宗益，陸亞清，朱美芳, 界面聚合制備聚苯胺納米纖維，上海大學(xué)出版社(2009)

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曾在香港科技大學(xué)物理系楊志宇教授(Jason Yang)課題組從事過(guò)科研工作，仍與楊教授保持密切聯(lián)系和合作意向。