個人簡介
姓名:姚英明
職稱:教授、博士生導師 部門:有機化學研究所
個人履歷
1990年四川大學化學系本科畢業(yè),1996年中國科學院長春應用化學研究所研究生畢業(yè),獲得理學博士學位,1997-1999年香港大學化學系博士后。1999.8蘇州大學化學化工學院任副教授,2004年破格晉升教授。任材料與化學化工學部教授,博士生導師,有機化學學科帶頭人,有機化學研究所所長,江蘇省有機化學國家級重點學科建設負責人,江蘇省有機合成重點實驗室主任,江蘇省化學化工學會理事,江蘇省化學化工學會有機化學專業(yè)委員會委員。主持完成2項國家自然科學基金面上項目和1項重點項目子項目,1項江蘇省自然科學基金青年創(chuàng)新人才項目及1項江蘇省屬高校自然科學重大基礎研究計劃項目。主持2項國家自然科學基金面上項目和1項國家自然科學基金重點項目子項目的研究工作。發(fā)表SCI源期刊論文120多篇,被SCI源期刊論文他引600多次。獲中國發(fā)明專利授權4項,2009年獲得江蘇省科技進步二等獎(排名第二),2010年中國石油和化學工業(yè)科學技術獎一等獎(排名第二)。“蘇州大學首批優(yōu)秀中青年學術骨干”,“蘇州市新世紀高級青年專業(yè)技術人才”培養(yǎng)對象。
研究領域
稀土金屬有機化合物的合成、結構及其催化性能;均相催化;稀土材料化學等。
主要論文
1.Synthesis and Structural Diversity of Heterobimetallic Lanthanide-Potassium Complexes and Catalytic Activity for Amidation of Aldehydes with Amines, B. Xu, L. L. Huang, Z. J. Yang, Y. M. Yao,* Y. Zhang, Q. Shen, Organometallics, 2011, , 3588.
2.Bimetallic aluminum alkyl complexes as highly active initiators for the polymerization of -caprolactone, W. Y. Li,W. T. Wu,Y. R. Wang, Y. M. Yao,*Y. Zhang Q. Shen, Dalton Trans., 2011, , 11378.
3.Lanthanide alkyl complexes supported by a pipeazidine-bridged bis(phenolate) ligand: Synthesis, structural characterization, and catalysis for the polymerization of L-lactaide and rac-lactide, Y. J. Luo, W. Y. Li, D. Lin, Y. M. Yao,* Y. Zhang, Q. Shen, Organometallics, 2010, , 3507.
4.Synthesis and characterization of amine bridged bis(phenolate) lanthanide aryloxides and their application in the polymerization of lactide, K. Nie, X. Y. Gu, Y. M. Yao,* Y. Zhang, Q. Shen, Dalton Trans., 2010, , 6832.
5.Synthesis and characterization of anionic rare-earth metal amides stabilized by phenoxy-amido ligands and their catalytic behavior for the polymerization of lactide, M. Lu, Y. M. Yao,* Y. Zhang, Q. Shen, Dalton Trans., 2010, , 9530
6.Facile syntheses of bimetallic ytterbium bisamides stabilized by a flexible bridged bis(phenolato) ligand and the high activity for the polymerization of L-lactide, Z. J. Zhang, X. P. Xu, S. Sun, Y. M. Yao,* Y. Zhang, Q. Shen, Chem. Commun., 2009, 7414.
7.Synthesis of Rare-Earth Metal Amides Bearing an Imidazolidine-Bridged Bis(phenolato) Ligand and Their Application in the Polymerization ofL-Lactide, Z. J. Zhang, X. P. Xu, W. Y. Li, Y. M. Yao,* Y. Zhang,Q. Shen, Inorg. Chem., 2009, , 5715.
8.Migration of amide to imine group of lanthanide Schiff base complexes: effect of amido group, D. W. Qin, F. B. Han, Y. M. Yao,* Y. Zhang, Q. Shen, Dalton Trans., 2009, 5535.
9.Synthesis, Reactivity, and Characterization of Sodium and Rare-Earth Metal Complexes Bearing a Dianionic N-Aryloxo-Functionalized β-Ketoiminate Ligand, H. M. Peng, Z. Q. Zhang, R. P. Qi, Y. M. Yao,* Y. Zhang, Q. Shen, Y. X. Cheng, Inorg. Chem., 2008, , 9828.
10.Synthesis, characterization and reactivity of heteroleptic rare earth metal bis(phenolate) complexes, R. P. Qi, B. Liu, X. P. Xu, Z. J. Yang, Y. M. Yao,* Y. Zhang, Q. Shen, Dalton Trans., 2008, 5016.
11.Controlled Syntheses, Characterization, and Reactivity of Neutral and Anionic Lanthanide Amides Supported by Methylene-Linked Bis(phenolate) Ligands, X. P. Xu, Z. J. Zhang, Y. M. Yao*, Y. Zhang, Q. Shen, Inorg. Chem., 2007, , 9379.
12.Synthesis, Reactivity, and Structural Characterization of Sodium and Ytterbium Complexes Containing New Imidazolidine-Bridged Bis(phenolato) Ligands, X. P. Xu, Y. M. Yao,* Y. Zhang, Q. Shen, Inorg. Chem., 2007, , 3743.
13.Synthesis and structural characterization of novel mixed-valent samarium and divalent ytterbium and europium complexes supported by amine bis(phenolate) ligands, H. D. Guo, H. Zhou, Y. M. Yao,* Y. Zhang, Q. Shen, Dalton Trans., 2007, 3555
14.Synthesis and Structural Characterization of b-diketiminate-Lanthanide Amides and Their Catalytic Activity for the Polymerization of Methyl Methacrylate and -Caprolactone, Y. M. Yao,* Z. Q. Zhang, H. M. Peng, Y. Zhang, Q. Shen, J. Lin, Inorg. Chem., 2006, , 2175.
15.Homopolymerization of Cyclic Esters Initiated by Lanthanide Isopropoxides Supported by 2,2u2019-Ethylene-bis(4,6-di- - butylphenolate) Ligands, X. P. Xu, Y. M. Yao,* M. Y. Hu, Y. Zhang, Q.i Shen, J. Polym. Sci., Part A: Polym. Chem., 2006, , 4409.
16.Synthesis, Reactivity and Characterization of Amine Bis(phenolate) Lanthanide Complexes and their Application in the Polymerization of -Caprolactone, Y. M. Yao,* M. T. Ma, X. P. Xu, Y. Zhang, Q. Shen, W.-T. Wong, Organometallics, 2005, , 4014.
17.Carbon-Bridged Bisphenolate Lanthanide Alkoxides: Syntheses, Structures and their Application in the Controlled Polymerization of -Caprolactone, Y. M. Yao,* X. P. Xu, B. Liu, Y. Zhang, Q. Shen, W.-T. Wong, Inorg. Chem., 2005, , 5133.