基本信息
姓 名: 劉國生
性 別: 男
職 稱: 研究員
學(xué) 歷: 研究生
通訊地址: 上海市零陵路345號金屬有機(jī)國家重點(diǎn)實(shí)驗(yàn)室
簡歷
1991,9-1995,7南京理工大學(xué)化工學(xué)院，獲工學(xué)學(xué)士； 1996,9-1999,8中科院大連化學(xué)物理研究所，獲理學(xué)碩士； 1999,9-2002,8中科院上海有機(jī)化學(xué)研究所，獲理學(xué)博士； 2003,3-2005,7美國Lehigh大學(xué)，博士后； 2005,8-2007,7美國威斯康辛大學(xué)麥迪遜分�；瘜W(xué)系,研究助理； 2007,7-中科院上海有機(jī)所，“百人計(jì)劃”入選者,研究員。
研究方向
本課題組的研究集中在有機(jī)化學(xué)，金屬催化和材料化學(xué)的前沿交叉區(qū)域，主要基于C-M鍵的基元反應(yīng)，通過設(shè)計(jì)和合成一些新型的金屬催化劑來實(shí)現(xiàn)有機(jī)分子的高選擇性轉(zhuǎn)化，并對反應(yīng)機(jī)理的進(jìn)行研究，從而能夠更多的了解這些金屬催化的反應(yīng)，對金屬的基元反應(yīng)更多的認(rèn)識。
專家類別
百人；研究員
職務(wù)
課題組長
代表論著
Wu, Liang; Qiu, Shuifa; Liu, Guosheng,* “Brønsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.” Org. Lett.
Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng;* “Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.” Chem. Eur. J
Liu, Guosheng;* Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: effic- ient synthesis of linear allylamine derivatives.” Angew. Chem. Int. Ed
Yin, Guoyin; Liu, Guosheng;* “Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.” Angew. Chem. Int. Ed.
Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li;* Macromolecules
Liu, Guosheng; Stahl, Shannon. S;* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.” J. Am. Chem. Soc
Liu, Guosheng; Stahl, Shannon. S;* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation”, J. Am. Chem. Soc
Liu, Guosheng; Jia, Li;* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”, Angw. Chem. Int. Ed.
Liu, Guosheng; Jia, Li;* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”, J. Am. Chem. Soc.
Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling of Allenoic Acids and a,b-Unsaturated Carbonyl Compounds through Tandem Intramolecular oxypalladation and Conjugate Addition Reactions”, Tetrahedron Lett.
Lei, Aiwen; Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino- L-xylitol”, J. Org. Chem
Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalladation of Alkyne with Allylic Compounds”, Tetrahedron Lett.
Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition”, Org. Lett.