姓名：張正彪

職稱：博士，教授、博士生導師

部門：高分子科學與工程系

博士（2003年9月~2007年12月），蘇州大學，高分子化學與物理

碩士（1997年9月~2000年6月），蘇州大學，高分子化學與物理

本科（1993年9月~1997年6月），蘇州大學，化學工程

2000年8月~至今 蘇州大學，材料與化學化工學部

2007年8月~2008年8月，新加坡國立大學，博士后（Research Fellow）

2012年2月~2013年2月，美國阿克倫大學，訪問學者 (Visiting Scholar)

2015年6月~2015年8月，日本名古屋大學，訪問教授 (Visiting Professor)

[1]國家自然科學基金面上項目“基于可逆Diels-Alder反應構建復雜拓撲鏈結構以及分子量/序列明確的聚合物”（21674072）；2017.1-2020.12，項目負責人；

[2]國家自然科學基金面上項目 “基于非共價鍵相互作用和可控自由基聚合的大分子精密合成”（21174094）；2012.1-2015.12，項目負責人；

[3] 國家自然科學基金面上項目 “室溫下零價鐵調控的“活性”/可控自由基聚合”（21174094）；2012.1-2015.12，項目負責人；

[4]國家自然科學基金青年基金項目“單電子轉移活性自由基聚合（SET-LRP）的機理研究”（20904036），2010.1-2012.12，項目負責人；

[5] 江蘇省高校自然科學研究計劃重大基礎研究項目"基于活性自由基聚合和分子間弱相互作用的大分子精密合成" (2012.8-2015.12)，項目負責人；

[6]江蘇省高校自然科學基金項目“ATRP表面接枝法制備抗菌和抗紫外功能性真絲織物的研究”（09KJB150010），2009.9-2011.12，項目負責人；

[7]江蘇省高校省級重點實驗室開放課題“絲素膜表面的AGET-ATRP改性以及其作為細胞生長載體的研究”（KJS0913），2009.9-2010.12，項目負責人；

[1] 2014年江蘇省高�！扒嗨{工程”優(yōu)秀青年骨干教師培養(yǎng)對象

[2] 2010年度蘇州大學蘇鑫科研獎；

[3] 2010年度教育部科技進步二等獎（排五）；

[4] 2010年度江蘇省科技進步二等獎（排五）；

[5] 2008年度蘇州大學優(yōu)秀博士論文；

[6] 2019年度國家杰出青年科學基金建議資助項目申請人

大分子結構設計及其精密合成；序列明確/可控聚合物的設計與合成；拓撲聚合物的合成；功能高分子的設計和合成。

1. Yuxuan Ji, Liuqiao Zhang, Xue Gu, Wei Zhang, NianchenZhou,Zhengbiao Zhang,*andXiulin Zhu. Sequence-Controlled Polymers with Furan-Protected Maleimide as aLatent Monomer.Angew. Chem. Int. Ed.2017,56, 2328-2333.2. Wei Chen, YanyanZhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou,Zhengbiao Zhang*and Xiulin Zhu. Shape-memory and self-healingpolyurethanes based on cyclic poly(ε-caprolactone).Polym. Chem.,2016, 7, 6789-6797.3. Junfei Zhao, Yanyan Zhou, Yu Zhou, Nianchen Zhou,Xiangqiang Pan,Zhengbiao Zhang*and Xiulin Zhu. A straightforward approach for the one-pot synthesis of cyclicpolymers from RAFT polymers via thiolu2013Michael addition.Polym. Chem.,2016, 7,1782-1791.4. Chunlai Ding, Caiwei Fan, Ganquan Jiang, XiangqiangPan,Zhengbiao Zhang*,JianZhu* and Xiulin Zhu. Photocatalyst-Free and Blue Light-Induced RAFT Polymerizationof Vinyl Acetate at Ambient Temperature.MacromolecularRapid Communications.2015,36, 2181-2185.5. Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang,Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu,Zhengbiao Zhang*, Kan Yue* andStephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like”Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered withCyclic Polystyrenes.Macromolecules2014,47, 4160-4168.6. ZhihaoHuang, Yanyan Zhou, Zimu Wang,Ying Li, Wei Zhang, Nianchen Zhou,ZhengbiaoZhangand Xiulin Zhu. Recent Advances of CuAAC Click Reaction In Building Cyclic Polymer.Chinese Journal of Polymer Science2017,35, 317-341. Reviewarticle.7. Zhaoxiong Cai, Weihong Lu, Feng Gao,Xiangqiang Pan, * Jian Zhu,ZhengbiaoZhang*Xiulin Zhu*. Diselenide-Labeled Cyclic Polystyrene with MultipleResponses: Facile Synthesis, Tunable Size, and Topology.Macromol. Rapid Commun.2016,37, 865-871.8. Shuangshuang Zhang, Lu Yin, Wei Zhang*,Zhengbiao Zhang* and XiulinZhu*. Synthesis of Diverse Cyclic-Brush Polymers with Cyclic Polystyrene asUniversal Template via Grafting-from Approach.Polym. Chem.,2016, 7,2112-2120.9. Qingqing Liu, Huaqiao Wu, Liuqiao Zhang, Yu Zhou,Wei Zhang, Xiangqiang Pan,ZhengbiaoZhang* and Xiulin Zhu. RAFT polymerization of N-vinylpyrrolidonemediated by cyanoprop-2-yl-1-dithionaphthalate in the presence of afluoroalcohol: the possibility of altering monomer properties by hydrogenbonding?Polym. Chem.,2016, 7, 2015-2021.10. Yunshu Wang, Shuangshuang Zhang, Laibing Wang, WeiZhang*, Nianchen Zhou,ZhengbiaoZhang* and Xiulin Zhu*. The Suzuki coupling reaction as apost-polymerization modification: a promising protocol for construction ofcyclic-brush and more complex polymers.Polym. Chem.,2015,6, 4669-4677.11. Feng Gao, Xiangqiang Pan,* Jian Zhu,Zhengbiao Zhang*, Wei Zhang andXiulin Zhu. Facile synthesis of well-defined redox responsivediselenide-labeled polymers via organoseleniummediated CRP and aminolysis. Polym. Chem.,2015,6,1367-1372.12. Caiwei Fan, Chunlai Ding, Xiangqiang Pan,Zhengbiao Zhang*, Jian Zhu*, andXiulin Zhu. A Straightforward Method For Preparing Well-Defined ResponsiveDiselenide-containing Polymers Based on ATRP.Macromolecular Rapid Communications.2015,36, 903-908.13. JunfeiZhao, Yanyan Zhou, Yiwen Li, Xiangqiang Pan, Wei Zhang, Nianchen Zhou, KeZhang,Zhengbiao Zhang*andXiulin Zhu*, Modular Construction ofMacrocycle-based Topological PolymersviaHigh-Efficient Thiol Chemistry,Polym.Chem.,2015,6,2879u20132891.14. Huaqiao Wu, Yingbo Wan, Wenxiang Wang, Yong Wang, NianchenZhou, Wei Zhang, Xiaohong Li,*ZhengbiaoZhang,* Xiulin Zhu, HydrogenBonding Promoting Controlled Radical Polymerization of 2-Vinyl Pyridine:Supramonomer for A Better Control,PolymerChemistry,2015,6, 2620-2625.15. Feng Gao, Xiangqiang Pan, Jian Zhu, ZhengbiaoZhang, Wei Zhang, Xiulin Zhu Diselenocarbamates, Novel Initiators in ATRP ofStyrene,J. Polym. Sci., Part A: Polym.Chem.2015,53, 1927-1933.16. Yuwei Gu, Junfei Zhao, Qingqing Liu, XiangqiangPan, Wei Zhang,Zhengbiao Zhang*,Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomersat room temperature: a promising catalyst system for CRP.Polym. Chem.,2015,6, 359-363.17. Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang,Zhiwei Lin, Xiulin Zhu, Qiang Fu,ZhengbiaoZhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis ofmacrocyclic giant surfactants tethered with two different polyhedral oligomericsilsesquioxanes at distinct ring locations via four consecutive"click" reactions.Polym.Chem.,2015,6, 827-837.18. Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang,Xiangqiang Pan,Zhengbiao Zhang*,Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymerto "clickable" thiol group via the versatile sodium azide.Polym. Chem.,2014,5, 5546-5550.19. Wenxiang Wang, Junfei Zhao, Nianchen Zhou, JianZhu, Wei Zhang, Xiangqiang Pan,ZhengbiaoZhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerizationin the Presence of Zero-Valent Metals: from Components to PrecisePolymerization.Polym. Chem.2014,5, 3533-3546. Review Article.20. Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, WeiZhang,Zhengbiao Zhang* andXiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groupsfrom RAFT-made polystyrene: producing controllable bimodal molecular weightdistribution.Polym. Chem.2014,5, 1992-1998.21. Zhigui Zheng, Wenxiang Wang, Yuan Zhou,Zhengbiao Zhang* and Xiulin Zhu*.Manganese(III) acetylacetonate initiated RAFT olymerizations: an alternativeand versatile RAFT nitiator.Polym. Chem.2014,5, 37-42.22. Ye Cai, Jinjie Lu, Feng Zhou, Xiaoji Zhou, NianchenZhou*,Zhengbiao Zhang*,Xiulin Zhu* Cyclic Amphiphilic Random Copolymers Bearing Azobenzene SideChains: Facile Synthesis and Topological Effects on Self-Assembly andPhotoisomerization.Macromol. RapidCommun.2014,35, 901?907.23. YuweiGu, Junfei Zhao, Qingqing Liu, Nianchen Zhou,Zhengbiao Zhang*,Xiulin Zhu*. Zero-valent iron (Fe(0)) mediated RAFT miniemulsionpolymerization: a facile approach for the fabrication of Fe(0)-encapsulatedpolymeric nanoparticlesPolym. Chem.,2014,5, 4215?4218.24. Wenxiang Wang, Junfei Zhao, Huali Yu, NianchenZhou,Zhengbiao Zhang*,Xiulin Zhu*. Simultaneously improving controls over molecular weight and stereoregularity ofPoly(4-vinylpyridine) via a hydrogen bonding-facilitated controlled radicalpolymerization.Polymer2013,54, 3248-3253.25. Xiaofei Zhang, Yang Wu, Jun Huang, Xuelang Miao,Zhengbiao Zhang*, Xiulin Zhu*.Copper(0)-Mediated Radical Polymerization Of Styrene At Room Temperature.Chinese.J.Polym. Sci.2013,31, 702-712.26. Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao,Zhengbiao Zhang*and XiulinZhu*. Hydrogen bonding assisted reversible-deactivation radicalcopolymerization of 4-vinylpyridine and styrene: a facile approach foradjusting polymerization behavior, polymer composition.Polym. Chem.2013,4, 3575-3581.27. Xiaofei Zhang, Wenxiang Wang, Kai Guo, ChrysWesdemiotis,Zhengbiao Zhang*,Xiulin Zhu*. Zero-valent metal catalyzed radical-induced adjustableremoval/modification of thiocarbonylthio end groups of RAFT polymer at ambienttemperature.Polym. Chem.2013,4, 637-644.28. Yiyu Zhan,ZhengbiaoZhang*, Xiangqiang Pan, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. A CyclicSelenium-Based Reversible Addition-Fragmentation Chain Transfer Agent MediatedPolymerization of Vinyl Acetate.J.Polym. Sci., Part A: Polym. Chem.2013,51, 1656-1663.29. Wenxiang Wang, Junfei Zhao, Wei Zhang, Jian Zhu,Zhengbiao Zhang*, Xiulin Zhu*.Ligand-Free SET-DTLRP of MMA at Room Temperature.J.Polym. Sci., Part A: Polym. Chem.2013,51, 1872-1879.30. Xing Zhu, Nianchen Zhou*, Jian Zhu,Zhengbiao Zhang*, Wei Zhang,Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. High-Effi ciency Preparation ofMacrocyclic Polymers via a Circulatory Extraction-Cyclization Strategy.Macromol. Chem. Phys.2013,214, 1107-1113.31. Xing Zhu, Nianchen Zhou*, Jian Zhu,Zhengbiao Zhang*, Wei Zhang,Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*.A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryatesin One Pot.Macromol. Rapid Commun.2013,34, 1014-1019.32. Wenxiang Wang,ZhengbiaoZhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. Favorablehydrogen bonding in room-temperature Cu(0)-mediated controlled radicalpolymerization of 4-vinylpyridine.Polym.Chem.2012,3, 2731-2734.33. Junfei Zhao, Wenxiang Wang,Liangjiu Bai, Lili Zhou, Zhenping Cheng,Zhengbiao Zhang*, Xiulin Zhu*. Reversible-deactivation radical polymerizationmediated byCuSO₄?5H₂O: an alternative and promising copper(II)-basedcatalyst.Polym. Chem.2012,3, 3220-3223.34. Lili Zhou,ZhengbiaoZhang*, Wenxiang Wang, Zhenping Cheng, Nianchen Zhou, Jian Zhu, WeiZhang, Xiulin Zhu*. Zero-Valent Bimetallic Iron/Copper Catalyzed SET-LRP: ADual Activation by Zero-Valent Iron.J.Polym. Sci., Part A: Polym. Chem.2012,50, 936-943.35. Wenxiang Wang,ZhengbiaoZhang*, Yang Wu, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang,Xiulin Zhu*. Ligand-Free Cu(0)-Mediated Controlled Radical Polymerization ofMethyl Methacrylate at Ambient Temperature.J.Polym. Sci., Part A: Polym. Chem.2012,50, 711-719.36. Huali Yu,ZhengbiaoZhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Wei Zhang, XiulinZhu*. ATRP of Styrene Catalyzed by Elemental Fe(0) and Br2: An Easy andEconomical ATRP Process.J.Polym. Sci., Part A: Polym. Chem.2012,50, 2182-2187.37. Huali Yu, Yang Wu, Jinlong Gao, Wenxiang Wang,Zhengbiao Zhang*, Xiulin Zhu*.Copper(0)-Mediated Radical Copolymerization of Vinyl Acetate and Acrylonitrilein DMSO at Ambient Temperature.J.Polym. Sci., Part A: Polym. Chem.2012,50, 4983-4989.38. Huali Yu, Qifeng Chen,Zhengbiao Zhang*, Jian Zhu, Zhenping Cheng, Nianchen Zhou,Wei Zhang, Xiulin Zhu*. 60Co γ-irradiation-initiated RAFT polymerization of VAcat room temperature.React.Funct. Polym.2012,72, 153-159.39. Lili Zhou,ZhengbiaoZhang*, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, XiulinZhu*. Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization ofMethyl Methacrylate and Styrene at Ambient Temperature.Macromol. Chem. Phys.2012,213, 439-446.40. Qin Zhang,ZhengbiaoZhang*Wenxiang Wang, Jian Zhu, Zhenping Cheng, Nianchen Zhou, WeiZhang, Xiulin Zhu*. SET-RAFT of MMA Mediated by Ascorbic Acid-Activated CopperOxide.J. Polym. Sci., Part A:Polym. Chem.2012,50, 1424-1433.