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  • 龔軍芳

    龔軍芳

    龔軍芳,教授、碩士生導(dǎo)師,河南省教育廳學(xué)術(shù)技術(shù)帶頭人。1992年南開(kāi)大學(xué)化學(xué)系畢業(yè);1995年獲南開(kāi)大學(xué)理學(xué)碩士學(xué)位;1998年在中國(guó)科學(xué)院化學(xué)研究所獲博士學(xué)位。

    個(gè)人簡(jiǎn)介

    龔軍芳,教授、碩士生導(dǎo)師,河南省教育廳學(xué)術(shù)技術(shù)帶頭人。1992年南開(kāi)大學(xué)化學(xué)系畢業(yè);1995年獲南開(kāi)大學(xué)理學(xué)碩士學(xué)位;1998年在中國(guó)科學(xué)院化學(xué)研究所獲博士學(xué)位。1999.10~2001.09在鄭州大學(xué)化學(xué)系博士后流動(dòng)站工作;2001.10-2003.2在法國(guó)巴黎國(guó)家高等化學(xué)學(xué)校 (Ecole Nationale Superieure de Chimie de Paris) 從事天然產(chǎn)物Ambruticin合成新方法研究。2003年-至今在鄭州大學(xué)化學(xué)系工作。

    研究方向及成就

    主要從事金屬有機(jī)化學(xué)和均相催化化學(xué)研究,先后在等期刊上發(fā)表學(xué)術(shù)論文40余篇 (其中SCI收錄論文30余篇)。近年來(lái),主持完成教育部留學(xué)回國(guó)人員科研啟動(dòng)費(fèi)、河南省自然科學(xué)基金、鄭州大學(xué)引進(jìn)人才科研啟動(dòng)費(fèi)和鄭州大學(xué)校級(jí)青年骨干教師等項(xiàng)目;作為主要人員,參與完成2項(xiàng)國(guó)家自然科學(xué)基金項(xiàng)目和2項(xiàng)河南省杰出人才創(chuàng)新基金。目前主持國(guó)家自然科學(xué)基金項(xiàng)目1項(xiàng)。參與翻譯、編寫(xiě)著作3部,獲專利3項(xiàng)。

    近年來(lái)主要論文

    1. Jun-Long Niu, Qing-Tao Chen, Xin-Qi Hao, Qing-Xiang Zhao, Jun-Fang Gong*, Mao-Ping Song*. “Diphenylprolinol-derived Symmetrical and Unsymmetrical Chiral Pincer Pd(II) and Ni(II) complexes: Synthesis via One-pot Phosphorylation/metalation Reaction and C-H Activation.” Organometallics 2010, 29(9), 2148-2156.

    2. Ben-Shang Zhang, Wei Wang, Dan-Dan Shao, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C-H Activation, Crystal Structures and Catalytic Studies.” Organometallics 2010, 29(11), 2579-2587.

    3. Jun-Fang Gong, Yan-Hui Zhang, Mao-Ping Song*, Chen Xu. “New PCN and PCP Pincer Palladium(II) Complexes: Convenient Synthesis via Facile One-pot Phosphorylation/Palladation Reaction and Structural Characterization.” Organometallics 2007, 26(25), 6487-6492.

    龔軍芳

    4. Li-Yuan Wu, Xin-Qi Hao, Yan-Xiao Xu, Min-Qiang Jia, Ya-Nan Wang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Pt(II) and Pd(II) Complexes with 1,3-Bis(2’-imidazolinyl)benzene: Synthesis via Direct Metalation, Characterization, and Catalytic Activity in the Friedel-Crafts Alkylation Reaction.” Organometallics 2009, 28(12), 3369-3380.

    5. Ben-Shang Zhang, Chao Wang, Jun-Fang Gong*, Mao-Ping Song*. “Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions.” J. Organomet. Chem. 2009, 694, 2555-2561.

    6. Xin-Qi Hao, Ya-Nan Wang, Jun-Rui Liu, Kun-Lun Wang, Jun-Fang Gong,* Mao-Ping Song*. “Unsymmetrical, oxazolinyl-containing achiral and chiral NCN pincer ligand precursors and their complexes with palladium(II).” J. Organomet. Chem. 2010, 695, 82-89.

    7. Kai Xu, Xin-Qi Hao, Jun-Fang Gong,* Mao-Ping Song,* and Yang-Jie Wu. “Room Temperature Suzuki Reactions in Aqueous Media under Air by Palladium(II) Complexes with Pyrazole Derived Ligands.” Aust. J. Chem. 2010, 63, 315-320.

    8. Chen Xu, Jun-Fang Gong*, Su-Fang Yue, Yu Zhu, Yang-Jie Wu*. “Tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes: synthesis, crystal structures and application in Suzuki and Heck reactions.” 2006, 4730-4739.

    9. Chen Xu, Jun-Fang Gong*, Tao Guo, Yan-Hui Zhang, Yang-Jie Wu*. “Cyclopalladated ferrocenylimine complexes with dicyclohexylphosphino- biphenyl ligands: Synthesis, crystal structures and their use as highly efficient catalysts for Suzuki reaction of aryl chlorides.”2008, , 69-76.

    10. Chen Xu, Jun-Fang Gong*, Yang-Jie Wu*. “Amination of aryl chlorides in water catalyzed by cyclopalladated ferrocenylimine complexes with commercially available monophosphinobiaryl ligands.” 2007, , 1619-1623.

    11. Xin-Qi Hao, Jun-Fang Gong*, Chen-Xia Du, Li-Yuan Wu,Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands.” 2006, , 5033-5036.

    12. Chen Xu, Jun-Fang Gong*, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*.“Synthesis, Characterization and Crystal Structures of Three Pyridine- Cyclopalladated Ferrocenylimine Complexes, and Their Catalysis in Suzuki Reactions.” 2007, , 190-195.

    13. Jun-Fang Gong*, Xin-Heng Fan, Chen Xu, Jin-Lei Li, Yang-Jie Wu*, Mao-Ping Song. “New cycloplatinated complexes with 2-arylimidazolines: synthesis, crystal structures and photophysical properties.” 2007, , 2006-1013.

    14. Junfang Gong, Guangyu Liu, Chenxia Du, Yu Zhu, Yangjie Wu*. “Efficient Suzuki coupling of aryl chlorides catalyzed by tricyclohexylphosphine adducts of cyclopalladated ferrocenylimines.” 2005, 3963-3969.

    15. Chen Xu, Jun-Fang Gong*, Mao-Ping Song, Yang-Jie Wu*. “Catalysis of the coupling reaction of aryl chlorides with bis(pinacolato)diboron by tricyclohexylphosphine- cyclopalladated ferrocenylimine complexes.” 2009, , 175-179.

    16. Xin-Qi Hao, Fang Liu, Bi Zhang, Mei-Ling Jiang, Jun-Fang Gong, Mao-Ping Song*. “Cyclopalladated complexes of 2-(m-nitrophenyl)imidazolines: synthesis, characterization and catalytic activity in the Suzuki reaction under mild conditions.” 2010, , 271-277.

    17. Xin-Qi Hao, Jun-Fang Gong*, Wen-Tao Song, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and crystal structures of mono-, bis- as well as tris-mercurated complexes with ferrocenylazines.” 2007, , 371-375.

    18. Jun-Fang Gong*, Chen Xu, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, characterization and crystal structures of two pyridine-cyclopalladated ferrocenylimine complexes.” 2007, , 1000-1004.

    19. GONG Jun-fang*, ZHANG Yan-hui, FAN Xin-heng, WANG Da-wei, SONG Mao-ping, WU Yang-jie. “Synthesis, Structural Characterization of Ferrocenyl Iminophosphines and Amidophosphines as Well as Their Application in the Suzuki Reaction.”2007,, 683-687.

    20. Jun-Fang Gong*, Da-Wei Wang, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis and Structural Characterization of Mercury(II) Complexes with a Novel Ferrocenyliminophosphine.” 2006, (), 2115-2120.

    21. Chen Xu, Jun-Fang Gong, Yan-Hui Zhang, Yu Zhu, Chen-Xia Du, Yang-Jie Wu. “Synthesis, characterization and crystal structures of a novel 1,1u2019-bisferrocenylimine and its monocyclopalladated derivative.” 2006, , 456-459.

    22. Ling-Zhi Du, Jun-Fang Gong*, Chen Xu, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and structures of novel diastereomeric cyclopalladated ferrocenylimines derived from chiral b-amino alcohols.” . 2006, , 410-414.

    23. Ling-Zhi Du, Jun-Fang Gong*, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and the crystal structures of novel achiral and chiral a-ferrocenyl a-aminophosphine oxides.” 2006, , 529-532.

    24. Junfang Gong, Guangyu Liu, Yu Zhu, Chenxia Du, Maoping Song, Yangjie Wu*. “Synthesis, Characterization and Catalytic Activity in Suzuki Reaction of Cyclopalladated Ferrocenylimine Tri- phenylphosphine complexes.” 2006, (), 1266-1271.

    25. Junfang Gong,Chen Xu, Yangjie Wu. “Transition-Metal Catalyzed α-Arylation of Carbonyl Derivatives and Compounds with Acidic Hydrogen.” 2006, (), 752-760.

    26. Junfang Gong, Eric Bonfand, Eric Brown, Gilles Dujardin, Véronique Michelet and Jean-Pierre Genêt. “Remarkable stereocontrol in the synthesis of 1,2,3,5-tetrasubstituted tetrahydropyrans via an asymmetric heterocycloaddition of a ketone-derived enol ether. ” 2003, 2141-2144.

    專利目錄

    27. 龔軍芳,吳養(yǎng)潔,徐晨. “環(huán)鈀化二茂鐵亞胺-氨基膦配合物及其應(yīng)用.” 專利號(hào):ZL 2006 1 0048594.9

    28. 宋毛平,龔軍芳,郝新奇,武利園,汪亞男,吳養(yǎng)潔. “手性和非手性雙咪唑啉基苯類化合物及合成方法.” 專利號(hào):ZL 2007 1 0053911.0

    29. 宋毛平,郝新奇,龔軍芳,林昆華,張碧,李玉江. “鉗形雙咪唑啉鈀化合物及其在Suzuki反應(yīng)中的應(yīng)用.” 專利號(hào):200710054070.5

    參與編寫(xiě)、翻譯的著作目錄

    1、現(xiàn)代有機(jī)反應(yīng) 胡躍飛 林國(guó)強(qiáng)主編 第五卷《金屬催化反應(yīng)》 撰寫(xiě)《傅-克反應(yīng)》一章 2008.12 化學(xué)工業(yè)出版社 ISBN 978-7-122-03784-8

    2、有機(jī)立體化學(xué)導(dǎo)論(譯著)國(guó)外名校名著系列 2007.1 化學(xué)工業(yè)出版社 ISBN 978-7-5025-8940-0 翻譯第13-16章等

    3、有機(jī)化學(xué)學(xué)習(xí)指導(dǎo) 國(guó)家理科基地名牌課程建設(shè)參考書(shū) 2008.1 鄭州大學(xué)出版社 ISBN 978-7-81106-743-9 參編

    TAGS: 化學(xué)系 教育 鄭州大學(xué)
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