朱士正,男,1947年12月出生,
中國科學(xué)院上海有機(jī)化學(xué)研究所研究員,課題組長。
教育經(jīng)歷
1980.7 畢業(yè)于貴陽師院化學(xué)系
1982.2 在中國科學(xué)院上海有機(jī)化學(xué)研究所獲理學(xué)碩士學(xué)位
1985.2 在中國科學(xué)院上海有機(jī)化學(xué)研究所獲理學(xué)博士學(xué)位
1985.8-1986.10 美國Polytechnic University of NewYork做博士后研究,導(dǎo)師Prof.O.Vogl,從事頭-頭高分子研究
1986.11-1989.3 美國Clemson University繼續(xù)博士后研究,師從著名氟化學(xué)D.D.DesMarteau,從事含氟超強(qiáng)酸的研究
研究領(lǐng)域
有機(jī)氟化學(xué)研究
主要工作成就
1984年4月回國后先后承擔(dān)多項(xiàng)國外公司合同任務(wù)及攻關(guān)項(xiàng)目研究(如: OxyChem. Co. ,DuPont Co. 和 AlliedSignal Co 等)。并同時(shí)開展“含氟活潑中間體”這一基礎(chǔ)研究。該項(xiàng)目曾先后獲上海市科委和國家自然科學(xué)基金會(huì)資助,現(xiàn)已結(jié)題。
目前又繼續(xù)承擔(dān)國家自然科學(xué)基金會(huì)面上項(xiàng)目“N-全氟烷砜基磷酰胺”和參加九五重點(diǎn)項(xiàng)目“有機(jī)氟化學(xué)反應(yīng)及應(yīng)用”的研究。迄今已在國內(nèi)外核心期刊上共發(fā)表論文50多篇。
自1989年回國以年來曾四次赴美進(jìn)行短期合作研究(每次四個(gè)月左右)。參加在國內(nèi)外召開的有關(guān)國際學(xué)術(shù)會(huì)議12次,其中四次為口頭報(bào)告,二次為大會(huì)邀請(qǐng)報(bào)告,余為墻報(bào)展講。
曾負(fù)責(zé)籌辦在國內(nèi)召開的國際學(xué)術(shù)會(huì)議二次,全國會(huì)議一次。
培養(yǎng)碩士研究生四名,三名已畢業(yè),一名在讀。并承擔(dān)碩士課程“物理有機(jī)”和“氟譜”。
已發(fā)表文章
1. 1,1,3,3-Tetraoxopolyfluoro-1,3-dithiacycloalkanes CH2SO2(CF2)nSO2 ( n = 2~5) and 2-substituted derivatives
S. Z. Zhu, W. T. Pennington and D. D. DesMarteau Inorg. Chem 34 (1995) 793.
2. A convenient synthetic method for N-perfluoroalkanesulfonyl sulfilimines and sulfoximides
S. Z. Zhu, J. Zhang and B. Xu J. Fluorine Chem. 71 (1995) 81.
3. Synthesis of perfluoroalkanesulfonylaminoalkylphosphonic acids
S. Z. Zhu and X. L. Jin J. Fluorine Chem. 72 (1995) 19.
4. Study of the electron-transfer initiated reaction of N, N-dichloro-5-iodo-3-oxa- octafluoropentane sulfonyl amide and carbomethoxydifluoromethane sulfonyl
azide with 2-methyl-2- nitrosopropane
C. M. Zhou, S. Z. Zhu, Y. H. Zhang, B. Xu, J. Zhang, X. K. Jiang
J. Fluorine Chem. 73 (1995) 175.
5. Synthesis and reaction of ?,??? di(trifluoroacetyl)ethylene derivatives, (CF3CO)2C=CR1R2
S. Z. Zhu, B. Xu and J. Zhang J. Fluorine Chem. 74 (1995) 167.
6. Reactions of fluorine-containing N-sulfinylamides with carboxylic acides and
acid anhydrides
S. Z. Zhu, B. Xu and J. Zhang J. Fluorine Chem. 74 (1995) 203.
7. A convenient synthesis of N-perfluoroalkanesulfonylphosphoramidates
S. Z. Zhu, J. Zhang and B. Xu J. Fluorine Chem. 78 (1996)183.
8. Reactions of N-sulfinylperfluoroalkanesulfonyl-amine with alkene oxides
S. Z. Zhu, C.Y. Qin and B. Xu J. Fluorine Chem. 79 (1996) 49.
9. Synthesis of 2-perfluoroalkyl substituted acetals
S. Z. Zhu, C.Y. Qin and B. Xu J. Fluorine Chem. 79 (1996) 77.
10. Synthesis of novel (perfluorophenylamino) benzylphosphonates and phosphonic acids
S. Z. Zhu, B. Xu, Jie Zhang and C.Y. Qin
Phosphorus, Sulfur, and silicon 112 (1996) 219.
11. Preparation of 2-substituted perfluoroalkylsulfones
S. Z. Zhu, C.Y. Qin and B. Xu
Phosphorus, Sulfur,and silicon 113 (1996) 259.
12. Synthesis of 1-(N-Perfluoroalkanesulfonylamino)-2,2,2-(trichloroethyl)-
dialkylphos phonates and Phosphonic Acids
Bin Xu and S. Z. Zhu Heteroatom Chemistry 8 (1997) 309.
13. N-Perfluoroalkanesulfonyl-phosphoramides via an Improved Atherton-Todd Reaction
S. Z. Zhu, J. Zhang, B. Bin and C. Y. Qin Org. Prep. Proced. Int. 29 (1997) 352.
14. Preparation of N,N-dialkyl-N`-perfluoroalkanesulfonylformamidines
RfSO2N=CHNR2 via Vilsmeier reagents
Guolin Xu, Bin Xu, Chaoyue Qin, Shizheng Zhu
J. Fluorine Chem. 84 (1997) 25-28.
15. Synthesis, Struture, and Reactions of Triphenylphosphine N-((Perfluoroalkyl)-
sulfonyl)imine and Triphenylarsine N-((Perfluoroalkyl)sulfonyl)imine
Shizheng Zhu, Bin Xu, Chaoyue Qin, and Guolin Xu
Inorg. Chem. 36 (1997) 4909-4911.