個(gè)人簡(jiǎn)介
周錫庚(1894—1963),字夢(mèng)白, 衢縣人。1918年浙江省醫(yī)藥專門學(xué)校藥科畢業(yè),留學(xué) 日本;貒(guó)后任上海中法藥廠廠長(zhǎng),以中華制藥公司名義監(jiān)制龍虎人丹。當(dāng)時(shí)日本仁丹占領(lǐng)中國(guó)市場(chǎng)。中法藥廠做大幅廣告,宣傳“中國(guó)人請(qǐng)服中國(guó)人丹”,以激發(fā)國(guó)人愛(ài)國(guó)熱情,自覺(jué)抵制日貨。龍虎人丹暢銷全國(guó)及南洋等地。
主要事跡
日本資本家對(duì)錫庚恨之入骨,1936年1月28日日本侵略軍進(jìn)犯上海時(shí),投擲炸彈企圖炸毀中法藥廠。上海淪陷后,日偽臨時(shí)政府對(duì)錫庚進(jìn)行威脅利誘,妄圖迫使不再生產(chǎn)龍虎人丹,遭嚴(yán)詞拒絕。還創(chuàng)制九一四藥膏、艾羅補(bǔ)汁等藥品及孩兒面等化妝品,暢銷全國(guó)。
1951年,任中國(guó)中醫(yī)院中西藥研究所研究員! 文化大革命”中被誣為“ 反動(dòng)學(xué)術(shù)權(quán)威”,1978年恢復(fù)名譽(yù)。著有《 藥用植物》等。
迄今共主持了20余項(xiàng)國(guó)家及省市部門科學(xué)基金研究課題,發(fā)現(xiàn)了20余種重要的稀土金屬有機(jī)新反應(yīng),如首例稀土金屬誘導(dǎo)的芳基取代烯醇配體的親電共扼加成反應(yīng),稀土引發(fā)的硅自由基催化反應(yīng),Me2SiO插入金屬-氮鍵反應(yīng)、氧插入稀土-硫鍵反應(yīng)等。發(fā)表研究論文110余篇。這些論文已被同行在《Chem. Rev.》; 《J. Am. Chem. Soc.》; 《Angew.Chem.Int. Ed.Engl.》等重要學(xué)術(shù)期刊上共引用500余次。獲國(guó)家教委科技進(jìn)步二等獎(jiǎng)2項(xiàng),安徽省教委科技進(jìn)步一等獎(jiǎng)1項(xiàng),上海市科技進(jìn)步三等獎(jiǎng)1項(xiàng)。曾獲上海市“ 曙光學(xué)者“、教育部“優(yōu)秀青年教師“、教育部“跨世紀(jì)優(yōu)秀人才“、“上海市優(yōu)秀學(xué)科帶頭人“等稱號(hào)。
研究領(lǐng)域
金屬有機(jī)化學(xué);基于稀土金屬參與的新有機(jī)合成方法學(xué);金屬導(dǎo)向的分子組裝、結(jié)構(gòu)、磁性和化學(xué)反應(yīng)。
代表性著作
在國(guó)內(nèi)外學(xué)術(shù)期刊發(fā)表論文110余篇,代表性著作有:
1.“SmCl3-Catalyzed C-Acylation of 1,3-Dicarbonyl Compounds and Malononitrile”, Organic Letters, 2007.
2.“Metallic Dysprosium-Induced Silyl Radical Reactions: Intermolecular Cyclization and Reduction of Alkynes and Imines”, Organometallics, 2007, 26, 2499.
3.“Selective Reaction Based on the Linked Diamido Ligands of Dinuclear Lanthanide Complexes”, Inorg. Chem. 2007, 46, 5252-5259.
4.“Synthesis and structural characterization of lanthanide complexes with the di- or tri-anionic diguanidinate ligand: New insight into the flexibility and distinct reactivity of the linked diguanidinate ligand”, Chem. Commun., 2007, 2190.
5.“Multiple NH Bond Activation: Synthesis and Reactivity of Functionalized Primary Amido Ytterbium Complexes”, Organometallics, 2007, 26, 1934.
6.“Crystal Engineering of Zinc and Copper Complexes Containing 3,5-Dimethylisoxazole-4-carboxylate Ligand via Ou2013H…N, Cu2013H…A (A = N, O and π) and Bifurcated Cu2013H…N/O Interactions”, CrystEngComm. 2007, 9, 35.
7.“Synthesis, Structural Characterization and Reactivity of Lanthanide Complexes Containing a New Methylene-bridged Indenyl-Pyrrolyl dianionic Ligand”, Organometallics, 2006, 25, 5165.
8.“Reactivity of lanthanocene amide complexes toward ketenes: Unprecedented organolanthanide-induced Conjugate Electrophilic Addition of Ketenes to Arenes”, Chem. Eur. J. 2006, 12, 6940.
9.“DyI2 Initiated Mild and Highly Selective Silyl Radical-catalyzed Cyclotrimerization of Terminal Alkynes and Polymerization of MMA”,Chem. Commun. 2006, 2066.
10.“Reactivity of Lanthanocene Hydroxides toward Ketenes, Isocyanate, Lanthanocene Alkyl and Triscyclopentadienyllanthanide Complexes”, Inorg. Chem. 2006, 45, 5867.