u008c 熱固性樹脂的合成改性及其工業(yè)應(yīng)用研究

Synthesis and Modification of Thermosets and Their Industrial Applications as Electronic, Structural and Composite Materials

u008d 聚合物材料的結(jié)構(gòu)表征和加工流變及力學(xué)性能研究

Structure Analysis of Polymers and Investigation on the Rheological and Mechanical Properties

l? 2009-2012 國家自然科學(xué)基金 “介觀粒子在聚合誘導(dǎo)粘彈相分離中的作用機(jī)制研究”

l? 2009-2012 聯(lián)合利華公司 “超親水材料的研究開發(fā)”

l? 2009-2012 奧地利AT&S公司 “PCB用環(huán)氧樹脂固化控制及性能研究”

l? 2009-2012 臺(tái)灣精曜科技公司 “太陽能薄膜電池表征體系的開發(fā)”

l? 2008-2010國家自然科學(xué)基金 “聚合過程中微纖結(jié)構(gòu)的原位生成機(jī)理研究”

l? 2008-2010教育部博士點(diǎn)基金 “可聚合剛?cè)崆抖蔚途畚镌诜磻?yīng)性溶劑中的微相分離”

l? 2008-2010 上海新天和樹脂公司 “易溶型不飽和聚酯粉末粘接劑的開發(fā)”

l? 2008-2011浙江科樂公司 “自清潔增硬防霧涂料的研制開發(fā)”

l? 2007-2010奧地利AT&S公司 “微電子材料及納米復(fù)合材料的研究”

l? 2005-2007 美國國民淀粉化學(xué)公司 “電子封裝材料的增韌研究”

l? 2010年負(fù)責(zé)完成易溶型不飽和聚酯粉末粘接劑的工業(yè)化生產(chǎn)；

l? 2009年負(fù)責(zé)完成單組份防霧涂料的開發(fā)及工業(yè)應(yīng)用;

l? 2008年負(fù)責(zé)完成印刷線路板光固化阻焊膜的開發(fā)；

l? 2008年負(fù)責(zé)完成塑料增硬涂料的開發(fā)生產(chǎn)；

l? 2006年負(fù)責(zé)完成新型熱固性液晶電子材料；

l? 2005年負(fù)責(zé)完成新型高性能聚合物水泥防水涂料的開發(fā)生產(chǎn)；

l? 2004年參與完成汽車工業(yè)用防霧涂料開發(fā)；

l? 2003年負(fù)責(zé)完成沼氣池防水涂料的開發(fā)并在湖北省定點(diǎn)生產(chǎn)；

l? 2002年參與完成高耐溫先進(jìn)復(fù)合材料基體樹脂開發(fā)，應(yīng)用于航空航天領(lǐng)域；

l? 2001年負(fù)責(zé)完成染發(fā)中間體合成及生產(chǎn)出口；

l? 1999年負(fù)責(zé)完成綠色脲醛膠粘劑開發(fā)轉(zhuǎn)讓；

l? 1998年負(fù)責(zé)環(huán)氧地坪以及聚氨酯系列涂料的國產(chǎn)化研究，技術(shù)轉(zhuǎn)讓六省一市；

l? 1998年負(fù)責(zé)完成電子封裝用有機(jī)硅改性酚醛樹脂開發(fā)；

l? 1997年參與完成高韌性先進(jìn)復(fù)合材料基體樹脂開發(fā)，應(yīng)用于航空航天領(lǐng)域；

l? 1997年完成航天工業(yè)用高性能環(huán)氧粘接劑；

l? 1996年參與完成“VLSI環(huán)氧塑封料”國產(chǎn)化開發(fā)；

l? 1995年參與完成電子封裝材料清模劑國產(chǎn)化研究；

l? 2009年與Univ. Rovira i Virgili合作獲西班牙優(yōu)秀聯(lián)合研究團(tuán)隊(duì)獎(jiǎng)

1. Yu YF*, Zhong XH, Su HH, Serra A. Simultaneous cationic polymerization and esterification of epoxy/anhydride system in the presence of polyoxometalate catalyst. Polymer 2010; 51: 1563-71.

2. Li L, Yu YF*, Su HH, Zhan GZ, Li SJ, Wu PY. The Diffusion Mechanism of Water Transport in Amine-Cured Epoxy Networks. Appl Spectrosc 2010; 64: 458-65.

3. Zhan GZ, Tang XL, Yu YF*, Li SJ. Biobased Cyanate Ester Composites with Epoxidized Soybean Oil and in situ Generated Nano-silica. Polym Eng Sci ASAP

4. Liu Y, Zhong XH, Yu YF*. Gelation behavior of thermoplastic-modified epoxy systems during polymerization-induced phase separation. Colloid Polym Sci 2010; 288: 1561-70.

5. Zhan GZ, Hu S, Yu YF*, Li SJ, Tang XL. The Study on Poly(ether sulfone) Modified Cyanate Ester Resin and Epoxy Resin Cocuring Blends. J Appl Polym Sci 2009; 113: 60-70.

6. Yu YF*, Zhong XH, Gan WJ. Conductive composites based on coreu2013shell polyaniline nanoclay by latex blending. Colloid Polym Sci 2009; 287: 487-93.

7. Yu YF*, Su HH, Gan WJ. Effects of Storage Aging on the Properties of Epoxy Prepregs. Ind Eng Chem Res 2009; 48: 4340-45.

8. Morell M, Ramis X, Ferrando F, Yu YF, Serra A. New improved thermosets obtained from DGEBA and a hyperbranched poly(ester-amide). Polymer 2009; 50: 5374-83.

9. Li L, Yu YF*, Wu QL, Zhan GZ, Li SJ. Effect of chemical structure on the water sorption of amine-cured epoxy resins. Corros Sci 2009; 51: 3000-06.

10. Gan WJ, Yu YF*, Liu XY, Wang MH, Li SJ. Kinetics of phase separation at the early stage of spinodal decomposition in epoxy resin modified with PEI blends. Colloid Polym Sci 2009; 287: 23-28.

11. Gan WJ, Xiong W, Yu YF*, Li SJ. Effects of the Molecular Weight of Poly(ether imide) on the Viscoelastic Phase Separation of Poly(ether imide)/Epoxy Blends. J Appl Polym Sci 2009; 114: 3158-67.

12. Foix D, Yu YF, Serra A, Ramis X, Salla JM. Study on the chemical modification of epoxy/anhydride thermosets using a hydroxyl terminated hyperbranched polymer. Eur Polym J 2009; 45: 1454-66.

13. Zhao L, Zhan GZ, Yu YF, Tang XL, Li SJ. Influence of attapulgites on cure-reaction-induced phase separation in epoxy/poly(ether sulfone) blends. J Appl Polym Sci 2008; 108: 953-59.

14. Zhan GZ, Zhao L, Hu S, Gan WJ, Yu YF*, Tang XL. A novel biobased resin-epoxidized soybean oil modified cyanate ester. Polym Eng Sci 2008; 48: 1322-28.

15. Yu YF*, Wang MH, Foix D, Li SJ. Rheological Study of Epoxy Systems Blended with Poly(ether sulfone) of Different Molecular Weights. Ind Eng Chem Res 2008; 47: 9361-69.

16. Yu YF*, Gan WJ, Liu XY, Li SJ. Liquid crystalline epoxy resin modified cyanate ester/epoxy resin systems. J Appl Polym Sci 2008; 109: 2964-72.

17. Wu Q, Li L, Yu YF*, Tang XL. The linear relations and living feature in cationic ring-opening copolymerization of epoxy/THF system. Colloid Polym Sci 2008; 286: 761-67.

18. Li L, Wu QL, Yu YF*, Tang XL, Li SJ, Wu PY. Near-IR Investigation on the Cationic Polymerization of Epoxy and Tetrahydrofuran Initiated by Heteropoly Acid. Acta Chim Sinica 2008; 66: 2263-70.

19. Yu YF*, Gao ZY, Zhan GZ, Li L, Li SJ, Gan WJ, Crivello JV. Formation of fibril structures in polymerizable, rod-coil-oligomer-modified epoxy networks. Chemistry-a European Journal 2007; 13: 2920-28.

20. Wang MH, Yu YF, Li SJ. Polymerization-induced phase separation in polyethersulfone modified epoxy resin systems: effect of curing reaction mechanism. Sci Chin B-Chem 2007; 50: 554-61.

21. Liu XY, Zhan GZ, Han ZW, Li SJ, Yu YF*. Phase morphology and mechanical properties of a poly(ether sulfone)-modified bismaleimide resin. J Appl Polym Sci 2007; 106: 77-83.

22. Liu XY, Yu YF*, Wang MH, Zhao L, Li L, Li SJ. Study on the polyethersulfone/bismaleimide blends: morphology and rheology during isothermal curing. J Mater Sci 2007; 42: 2150-56.

23. Gao ZY, Yu YF, Xu YZ, Li SJ. Synthesis and characterization of a liquid crystalline epoxy containing azomethine mesogen for modification of epoxy resin. J Appl Polym Sci 2007; 105: 1861-68.

24. Gan WJ, Zhan GZ, Wang MG, Yu YF*, Xu YZ, Li SJ. Rheological behaviors and structural transitions in a polyethersulfone-modified epoxy system during phase separation. Colloid Polym Sci 2007; 285: 1727-31.

25. Zhan GZ, Yu YF, Tang XL, Tao QS, Li SJ. Further study of the viscoelastic phase separation of cyanate ester modified with poly(ether imide). J Polym Sci Part B-Polym Phys 2006; 44: 517-23.

26. Yu YF, Wang MH, Liu XY, Zhao L, Tang XL, Li SJ. Synthesis and cure of liquid crystalline diallyl modifiers for bismaleimide resin. J Appl Polym Sci 2006; 101: 4366-71.

27. Yu YF, Wang MH, Gan WJ, Li SJ. Phase separation and rheological behavior in thermoplastic modified epoxy systems. Colloid Polym Sci 2006; 284: 1185-90.

28. Wang MH, Yu YF, Zhan GZ, Tang XL, Li SJ. Morphology and mechanical properties of poly (ether-imide)-modified polycyanurates. Colloid Polym Sci 2006; 284: 1379-85.

29. Liu XY, Zhan GZ, Yu YF*, Li SJ. Rheological study on structural transition in polyethersulfone-modified bismaleimide resin during isothermal curing. J Polym Sci Part B-Polym Phys 2006; 44: 3102-08.

30. Liu XY, Yu YF, Li SJ. Study on cure reaction of the blends of bismaleimide and dicyanate ester. Polymer 2006; 47: 3767-73.

31. Liu X, Yu YF, Li SJ. Viscoelastic phase separation in polyethersulfone modified bismaleimide resin. Eur Polym J 2006; 42: 835-42.

32. Yu YF, Wang MH, Gan WJ, Tao QS, Li SJ. Polymerization-induced viscoelastic phase separation in polyethersulfone-modified epoxy systems. J Phys Chem B 2004; 108: 6208-15.

33. Wang MH, Yu YF, Wu XG, Li SJ. Polymerization induced phase separation in poly(ether imide)-modified epoxy resin cured with imidazole. Polymer 2004; 45: 1253-59.

34. Tao QS, Gan WJ, Yu YF, Wang MH, Tang XL, Li SJ. Viscoelastic effects on the phase separation in thermoplastics modified cyanate ester resin. Polymer 2004; 45: 3505-10.

35. Tang XL, Zhang LX, Wang T, Yu YF, Gan WJ, Li SJ. Hydrodynamic effect on secondary phase separation in an epoxy resin modified with polyethersulfone. Macromol Rapid Comm 2004; 25: 1419-24.

36. Yu YF, Zhang ZC, Gan WJ, Wang MH, Li SJ. Effect of polyethersulfone on the mechanical and rheological properties of polyetherimide-modified epoxy systems. Ind Eng Chem Res 2003; 42: 3250-56.

37. Yu YF, Wang MH, Huang W, Li SJ. Synthesis of blue light emitting copolymers by oxidative coupling reaction. Synthetic Metals 2003; 135: 201-02.

38. Tao QS, Wang MH, Gan WJ, Yu YF, Tang XL, Li SJ, Zhuang JH. Studies on the phase separation of poly(ether imide)-modified cyanate ester resin. J Macromol Sci -Pure and Applied Chemistry 2003; A40: 1199-211.

39. Gan WJ, Yu YF, Wang MH, Tao QS, Li SJ. Viscoelastic effects on the phase separation in thermoplastics-modified epoxy resin. Macromolecules 2003; 36: 7746-51.

40. Gan WJ, Yu YF, Wang MH, Tao QS, Li SJ. Morphology evolution during the phase separation of polyetherimide/epoxy blends. Macromol Rapid Comm 2003; 24: 952-56.

41. Wu XG, Cui J, Tang XL, Yu YF, Li SJ. Studies on the phase separation of poly(ether imide) modified by tetraglycidyl-4,4 ’-diaminodiphenyl methane epoxy resin. Chem J Chin Univ 2000; 21: 1305-08.

42. Yu YF, Cui J, Chen WJ, Li SJ. Studies on the phase separation of polyetherimide modified tetrafunctional epoxy resin. II. Effects of the molecular weight. J Macromol Sci -Pure and Applied Chemistry 1998; A35: 121-35.

43. Yu YF, Cui J, Chen WJ, Li SJ. Studies on the phase separation of poly(ether imide) modified tetrafunctional epoxy resin - The effect of curing agent ratio. Chem J Chin Univ 1998; 19: 808-12.

44. Yu YF, Cui J, Chen R, Li SJ. Synthesis and characterization of new precursor polymers of poly[2-methoxy-5-(4-bromobutoxy)phenylene vinylene]. Chem J Chin Univ 1998; 19: 309-12.

45. Cui J, Yu YF, Li SJ. Studies on the phase separation of polyetherimide modified tetrafunctional epoxy resin. III. Morphology development of the blend during curing. J Macromol Sci -Pure and Applied Chemistry 1998; A35: 649-56.

46. Cui J, Yu YF, Li SJ. Studies on the phase separation of polyetherimide-modified epoxy resin, 3 - Part 1 - Morphology development of the blend during curing. Macromol Chem Phys 1998; 199: 1645-49.

47. Cui J, Yu YF, Chen WJ, Li SJ. Studies on the phase separation of polyetherimide-modified epoxy resin .2. Effect of molecular weight of PEI on the structure formation. Macromol Chem Phys 1997; 198: 3267-76.

48. 余英豐, 楊植震, 俞蕙, 詹國柱, 楊鹍. 固化溫度及填料對文物環(huán)氧膠粘劑性能的影響. 粘接 2009; 30: 79-80.

49. 蘇輝煌, 鐘新輝, 詹國柱, 余英豐*. 導(dǎo)電膠的研究進(jìn)展. 粘接 2008; 29: 28-33.

50. 劉小云, 余英豐, 甘文君, 唐曉林, 李善君. 熱塑性樹脂改性熱固性樹脂體系固化反應(yīng)誘導(dǎo)相分離研究進(jìn)展. 材料導(dǎo)報(bào) 2007, 21, 34-40.

51. 高宗永, 余英豐, 李善君. 先進(jìn)復(fù)合材料基體樹脂的增韌研究. 熱固性樹脂 2006, 21, (6), 6-10.

52. 余英豐，劉小云，李善君. 航空航天用環(huán)氧耐高溫膠粘劑研究. 粘接 2005, 26, 4-7.

53. 甘文君, 余英豐, 李善君. 熱塑性PEI改性TGDDM環(huán)氧樹脂的相分離研究. 工程塑料應(yīng)用 2003, 31, 5-8.

54. 李善君, 金堅(jiān)勇, 余英豐. 新型聚醚酰亞胺改性環(huán)氧樹脂結(jié)構(gòu)粘合劑. 熱固性樹脂 2001, 16, 8-11.

55. 金堅(jiān)勇, 余英豐, 唐曉林, 崔峻, 李善君, 王京成, 趙渠森, 華向陽, 蔡賢欽. 熱塑性聚醚酰亞胺改性四官能度環(huán)氧樹脂的相分離研究Ⅳ.聚醚酰亞胺用量的影響. 功能高分子學(xué)報(bào) 1999, 1

56. 余英豐, 陳睿, 李善君. 聚醚酰亞胺熱焓松馳的分子量依賴關(guān)系. 高分子材料科學(xué)與工程 1998, 14, 115-17.

申請專利：

57. 蘇輝煌, 余英豐*, 鐘新輝, 詹國柱. 一種自清潔環(huán)氧樹脂防霧涂料. CN201010105606.3

58. 鐘新輝,余英豐*,詹國柱,蘇輝煌. 一種纖維接觸角在線測量方法與裝置. CN200810034892.1

59. 李善君,余英豐*,高宗永. 用席夫堿型液晶環(huán)氧樹脂改性環(huán)氧樹脂的方法. CN200610118920.9

60. 李善君,余英豐*,高宗永.席夫堿型液晶環(huán)氧樹脂及其制備方法和應(yīng)用. CN200610118919.6

61. 余英豐*,李善君. 一種環(huán)氧樹脂組合物. CN200610117596.9

62. 余英豐,李善君. 一種1－萘肼的制備方法. CN200610023258.9

63. 余英豐,李善君.醇溶性聚對苯乙炔衍生物及其制備方法和應(yīng)用. CN200410053854.2

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