人物簡(jiǎn)介
2005年到2009年在日本大阪府立大學(xué),法國(guó)昂熱大學(xué),大阪大學(xué)以JST研究員身份從事科學(xué)研究。現(xiàn)任寧波工程學(xué)院化工學(xué)院副研究員。發(fā)表論文16篇。
研究方向
(1)有機(jī)功能材料;(2)原理型的分子器件;(3)分子識(shí)別。
研究興趣
Research Interests / 研究興趣
1.設(shè)計(jì)合成具有光、電、磁性質(zhì)的有機(jī)功能材料;研究這些有機(jī)材料結(jié)構(gòu)與性質(zhì)之間的關(guān)系
2.新型有機(jī)單分子器件(分子開(kāi)關(guān),分子整流器,分子導(dǎo)線)的設(shè)計(jì)與合成;運(yùn)用電化學(xué)以及有關(guān)光譜手段研究分子間及分子內(nèi)的電子轉(zhuǎn)移,能量轉(zhuǎn)移現(xiàn)象的光物理光化學(xué)的性質(zhì)。
3.分子識(shí)別,超分子化學(xué),雜環(huán)化學(xué)以及硫化學(xué)
研究項(xiàng)目
Research Projects/ 研究項(xiàng)目
1.主持承擔(dān)國(guó)家自然科學(xué)基金青年項(xiàng)目一項(xiàng),項(xiàng)目名稱為“多功能分晶體的制備和光照對(duì)其電、磁性質(zhì)的調(diào)控”(20902051),起止時(shí)間為2010.1-2012.12,現(xiàn)進(jìn)展順利。
2.主持承擔(dān)浙江省教育廳重點(diǎn)科研項(xiàng)目一項(xiàng),項(xiàng)目名稱“有機(jī)功能分子的設(shè)計(jì)、合成與性質(zhì)的研究”現(xiàn)進(jìn)展順利。
3.參與自然科學(xué)面上項(xiàng)目一項(xiàng),項(xiàng)目名稱為“環(huán)狀大pi分子體系的合成及性質(zhì)研究”(205072113)起止時(shí)間為2003.1-2005.12,現(xiàn)也結(jié)題。主要承擔(dān)人,排名第三。
4.參與國(guó)家重點(diǎn)基礎(chǔ)研究發(fā)展規(guī)劃子課題2000-2005(973:)項(xiàng)目題目為“特殊功能的有序組裝和自組裝”現(xiàn)也結(jié)題。主要承擔(dān)人,排名第5。
5.參與中國(guó)科學(xué)院創(chuàng)新重點(diǎn)項(xiàng)目“分子電子學(xué)Ⅱ”2004-2006現(xiàn)也結(jié)題。主要承擔(dān)人,排名第7。
發(fā)表論文
Selected Publications/ 部分發(fā)表論文
1.An Antiferromagnetic Molecular Metal Based on a New Bent-Donor Molecule, Xunwen. Xiao, T. Hayashi, H. Fujiwara, T. Sugimoto, S. Noguchi, Y. Weng, H. Yoshino, K. Murata, H. Aruga-Katori, J. Am. Chem. Soc 2007 129 12618-12619.
2.A Metallic (EDT-DSDTFVSDS)2·FeBr4 Salt: Antiferromagnetic Ordering of Spins of FeBr4 Ions and Anomalous Magnetoresistance Due to Preferential
- Interaction Toshiki Hayashi, Xunwen Xiao, Hideki Fujiwara, Toyonari Sugimoto, Hiroyuki Nakazumi, Satoru Noguchi, Tsutomu Fujimoto, Syuma Yasuzuka, Harukazu Yoshino, Keizo Murata, Takehiko Mori, and Hiroko Aruga-Katori, 2006 128 11746-11747. 3.A new fluorescence-switch based on supermolecular dyad with (tetraphenylporphyrinato)zinc(II) and tetrathiafulvalene units Xunwen Xiao, Wei Xu, Deqing Zhang, Hai Xu, Haiyan Lu and Daoben Zhu Journal of Materials Chemistry, 2005, (26), 2557 u2013 2561 4.Novel redox-fluorescence switch based on a triad containing tetrathiafulvalene and pyrene units with tunable monomer and excimer emissions Xunwen Xiao, Wei Xu, Deqing Zhang, Hai Xu, Lei Liu and Daoben Zhu, New J. Chem., 2005, 29 , 1291-1294 5.Two dication salts of ET: preparation and crystal structures of ET[Fe(CN)4(CO)2] Xunwen Xiao, Hai Xu, Wei Xu, Deqing Zhang, and Daoben Zhu Synthetic metals 2004 144 51-53 6.Dipotassium diaquabis(malonato-2O,O’)nickelate(II) dihydrate X. Xiao, W. Xu, Y. Li, B. Zhang and D. Zhu Acta Cryst. 2004. E60, m48-m49 7.4,5:4u2019,5u2019-bis(methylenedithio)tetrathiafulvalenium dichloride Xunwen Xiao, Hai Xu, Wei Xu, Deqing Zhang, and Daoben ZhuD. Zhu Acta Cryst. 2005 E61, o111-o113 8.Conducting Nanopearl Chains Based on the Dmit Salt Guanglei Cui, Wei Xu, Chaowei Guo, Xunwen Xiao, Hai Xu, Deqing Zhang, Lei Jiang, and Daoben Zhu J. Phys. Chem. B, 2004 108 (36), 13638-13642 9.Rose-like superhydrophobic surface based on conducting dmit salt Guanglei Cui Wei Xu, Xinhong Zhou, Xunwen Xiao, Lei Jiang , Daoben Zhu, Colloids and Surfaces A: Physicochem. Eng.Aspects 2006272 63u201367
10.Antiferromagnetic or Canted Antiferromagnetic Orderings of Fe(III) d Spins of FeX4 Ions in BEDT-TTFVO(S)·FeX4 (X = Cl, Br) [BEDT-TTFVO(S) = Bis(ethylenedithio)tetrathiafulvalenoquinone(-thioquinone)-1,3-dithiolemethide]
Mingxing Wang, Xunwen Xiao, Hideki Fujiwara, Toyonari Sugimoto, Satoru Noguchi, Takekazu Ishida, Takehiko Mori, and Hiroko Aruga Katori Inorg Chem 2007 463049-3056. 11.3 ,3u2019,4,4u2019-Tetrabutyl-5,5u2019-(biphenyl-4,4u2019-diyldiethynyl)bis(thiophene-2-carbonitrile) L. Liu, W. Xu, X.-W. Xiaoand D.-B. Zhu Acta. Cryst . 2007 E63, o3961
12.Weak Ferromagnetism in a Semiconducting ethylene-dithiodiselenadithia- fulvalenoquinone-1,3-diselenolemethide)2?FeBr4 Salt, T. Hayashi, Xunwen. Xiao, H. Fujiwara, T. Sugimoto, H. Nakazumi, S. Noguchi, H. Aruga-Katori, Inorg. Chem , 200746 8478-8480
13.Novel Sulfuru2013Selenium Exchange in Ethylenedioxy- and Ethylenedithiodithiadiselenafulvalenedithiolates Toshiki Hayashi, Xunwen Xiao, Yuhta Yamaji, Hideki Fujiwara, Toyonari Sugimoto, and Hiroyuki Nakazumi Vol.37, No.4 2008 428-429