工作和學(xué)習(xí)背景
現(xiàn)在主要從事有機(jī)硅、鍺和錫化學(xué),包括官能團(tuán)化有機(jī)硅單體和光學(xué)活性聚硅烷合成,穩(wěn)定的不飽和14-族有機(jī)金屬化合物合成及其結(jié)構(gòu)和它們的反應(yīng)活性的研究。
2005、05-至今杭州師范大學(xué)有機(jī)硅化學(xué)及材料技術(shù)教育部重點(diǎn)實(shí)驗(yàn)室 2003/06 u2013 2005/06 大阪府立大學(xué), 日本學(xué)術(shù)振興會外國人特別研究員(JSPS),Ogawa實(shí)驗(yàn)室
1998/09-2003/04 浙江大學(xué)有機(jī)化學(xué)研究所有機(jī)化學(xué)專業(yè),理學(xué)博士學(xué)位,
指導(dǎo)老師:張永敏 教授
1994/09-1998/06 河南師范大學(xué)化學(xué)系化學(xué)教育專業(yè),學(xué)士學(xué)位
論文
2002年以來發(fā)表的主要研究論文 1. A New Entry to the Construction of Si-Si Linkage: Sm/SmI2-Induced Efficient Reductive Coupling of Organochlorosilanes
Zhifang Li, Koichiro Iida,Yuri Tomisaka, Aya Yoshimura, Toshikazu Hirao, Akihiro Nomoto, Akiya Ogawa, Organometallics, 2007, 26(5), 1212-1216.
2. FERRIC CHLORIDE-CATALYZED DEOXYGENATIVE CHLORINATION OF CARBONYL COMPOUNDS TO HALIDES,
Zhifang Li, Chunqi Sheng, Huayu Qiu and Yongmin Zhang, Org. Prep. Proc. Int. 2007, 39(4), 429-432.
3. Direct Construction of Silicon-Silicon Bond by Using the Low-Valent Titanium
Guoqiao Lai, Zhifang Li, Jiabang Huang, Jianxiong Jiang, Huayu Qiu, Yongjia Shen, J. Organomet. Chem. 2007, 692, 3559-3562.
4. Controlled Introduction of Allylic Group to Chlorosilanes
Zhifang Li, Xiaojun Cao, Guoqiao Lai, Jinhua Liu, Yong Ni, Jirong Wu, Huayu Qiu, J. Organomet. Chem. 2006, 691, 4740-4746.
5. A Highly Efficient Reduction of Group 14 Heteroatom-Chlorine Single Bonds by Using Samarium Diiodide-Mediated Reaction Systems
Ikuyo Kamiya, Koichiro Iida, Zhifang Li, Yuri Tomisaka, Akiya Ogawa, J. Alloys Comp. 2006, 408-412, 437-440
6. Reductive Dimerization and Polymerization of Organochlorosilanes Mediated by a Sm/SmI2 Mixed System
Zhifang Li, Yuri Tomisaka, Akiya Ogawa, International Symposium Rare Earthsu2019 04 in Nara, Japan, November 7-12, 2004.
7. Low-Valent Samarium Promoted Reductive Polymerization of Organochlorosilanes
Zhifang Li, Akiya Ogawa, Rare Earths, 2004, 45, 232.
8. Novel Cyclization of Dimeric Dianions of Anils or Aldehydes with Triphosgene: A Safe and Efficient Synthesis of Substituted Imidazolidin u20132-ones and 4,5-Diaryl-1,3-dioxolan u20132-ones
Zhifang Li and Yongmin Zhang, Heteroatom Chem. 2003, 14 (1) 46-49.
9. Direct construction of quaternary carbon center utilizing an allylsamarium bromide reagent
Zhifang Li and Yongmin Zhang, Tetrahedron 2002, 58 (26), 5301.
10. Direct Construction of Quaternary Carbon Centre Utilizing an Organosamarium Reagent
Zhifang Li and Yognmin Zhang , Tetrahedron Lett. 2002, 42, 8507.
11. Low-Valent Titanium Induced Cyclization of Dimeric Dianions of Anil with Triphosgene: A Safe and Efficient Method for the Synthesis of Substituted Imidazolidine
Zhifang Li and Yongmin Zhang, Synth. Commun. 2002, 32(17), 2613-2618.
國際會議論文
1. International Symposium Rare Earthu2019 04 in Nara, Japan,
Reductive Dimerization and Polymerization of Organochlorosilanes Mediated by a Sm/SmI2 Mixed System, Li Zhifang, and Ogawa Akiya
2. China, Korea and Japan Tri-National Symposium on Silicon,2006, 11. 13-15th
Direct Construction of Silicon-Silicon Bond by Using the Low-Valent Titanium, Li Zhifang and Quoqiao Lai
3. 1st Pacific Symposium on Radical Chemistry (PSRC-1), November 15-16, 2004, Kanazawa, Japan
Low-valent Rare Earth Promoted Reaction of Chlorosilanes Li Zhifang, and Ogawa Akiya
主持過的主要科研項(xiàng)目
1. Development of Photo-induced New Catalytic Systems of Rare Earth Complexes (編號P03091, 240萬日元,日本學(xué)術(shù)振興會,2003年6月 29---2005年6月28)。
2.稀土金屬催化液晶聚硅烷的合成研究
杭州市留學(xué)人員科研活動擇優(yōu)資助項(xiàng)目 2萬,2006年12月-2007年12月。
3.有機(jī)硅介孔負(fù)載催化劑的制備及其對硅氫加成反應(yīng)的催化性能研究, 4萬,2007,4-2009,3。